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Merck

522805

Sigma-Aldrich

4-(二甲氨基)吡啶

≥99%

别名:

N,N-二甲基-4-吡啶胺, DMAP

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About This Item

经验公式(希尔记法):
C7H10N2
CAS号:
分子量:
122.17
Beilstein:
110354
EC號碼:
MDL號碼:
分類程式碼代碼:
12352000
PubChem物質ID:

化驗

≥99%

mp

108-110 °C (lit.)

SMILES 字串

CN(C)c1ccncc1

InChI

1S/C7H10N2/c1-9(2)7-3-5-8-6-4-7/h3-6H,1-2H3

InChI 密鑰

VHYFNPMBLIVWCW-UHFFFAOYSA-N

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應用

酰化反应的高效催化剂

其他說明

法律資訊

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

訊號詞

Danger

危險分類

Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 1

標靶器官

Nervous system

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

255.2 °F

閃點(°C)

124 °C

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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分析证书(COA)

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Dongfeng Wei et al.
International journal of biological macromolecules, 51(4), 471-476 (2012-06-19)
Sulfated modification of a polysaccharide obtained from Radix hedysari (RHP) was studied. Four sulfated derivatives (RHPS) with variable degrees of substitution (DS) were obtained by the chlorosulfonic acid method with ionic liquids (ILs) as solvent and 4-dimethylaminopyridine (DMAP) as catalyst.
Anitha Devadoss et al.
Analytical chemistry, 83(6), 2383-2387 (2011-03-03)
Metallopolymer-gold nanocomposites have been synthesized in which the metal complex-Au nanoparticle (NP) mole ratio is systematically varied by mixing solutions of 4-(dimethylamino) pyridine protected gold nanoparticles and a [Ru(bpy)(2)PVP(10)](2+) metallopolymer; bpy is 2,2'-bipyridyl and PVP is poly-(4-vinylpyridine). The impact of
Dongfeng Wei et al.
Glycoconjugate journal, 29(4), 167-172 (2012-04-27)
Phosphorylated modification of a polysaccharide obtained from Radix Hedysari (RHP) was studied. Three phosphorylated polysaccharides (RHPP) with variable degrees of substitution (DS(p)) were obtained with 4-dimethylaminopyridine (DMAP) and N, N' Dicyclocarbodiimide (DCC) as catalyst. The structures of RHPP were characterized
Zhan Zhang et al.
Molecules (Basel, Switzerland), 17(4), 3957-3968 (2012-04-03)
4-N,N-Dimethylaminopyridine (DMAP) as catalyst in combination with benzyl bromide was developed for the selective oxidation of methyl aromatics. DMAP exhibited higher catalytic activity than other pyridine analogues, such as 4-carboxypyridine, 4-cyanopyridine and pyridine. The sp3 hybrid carbon-hydrogen (C-H) bonds of
Eric G Klauber et al.
Journal of the American Chemical Society, 132(39), 13624-13626 (2010-09-17)
An efficient kinetic resolution of primary propargylic amines with s-factors of up to 56 is reported. The strategy is based on a dual catalytic approach, namely the use of a newly developed and easy-to-make thiourea-amide anion binding catalyst in combination

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