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Merck

519367

Sigma-Aldrich

3,5-双(三氟甲基)苯磺酰氯

97%

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About This Item

线性分子式:
(CF3)2C6H3SO2Cl
CAS号:
分子量:
312.62
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:

化驗

97%

mp

34-38 °C (lit.)

SMILES 字串

FC(F)(F)c1cc(cc(c1)S(Cl)(=O)=O)C(F)(F)F

InChI

1S/C8H3ClF6O2S/c9-18(16,17)6-2-4(7(10,11)12)1-5(3-6)8(13,14)15/h1-3H

InChI 密鑰

BTRCVKADYDVSLI-UHFFFAOYSA-N

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

226.4 °F - closed cup

閃點(°C)

108 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Highly enantioselective catalytic thiolysis of prochiral cyclic dicarboxylic anhydrides utilizing a bifunctional chiral sulfonamide.
Takashi Honjo et al.
Angewandte Chemie (International ed. in English), 44(36), 5838-5841 (2005-08-05)
Etienne Borré et al.
Beilstein journal of organic chemistry, 6, 1159-1166 (2010-12-18)
Seven novel Hoveyda-Grubbs precatalysts bearing an aminosulfonyl function are reported. Kinetic studies indicate an activity enhancement compared to Hoveyda's precatalyst. A selection of these catalysts was investigated with various substrates in ring-closing metathesis of dienes or enynes and cross metathesis.
Protein diffusion in porous gel filtration chromatography media studied by pulsed field gradient NMR spectroscopy.
Gibbs SJ, et al.
The Journal of Physical Chemistry, 96(18), 7458-7462 (1992)
Versatile chiral reagent for the highly enantioselective synthesis of either anti or syn ester aldols.
Corey EJ and Kim SS.
Journal of the American Chemical Society, 112(12), 4976-4977 (1990)

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