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Merck

460893

Sigma-Aldrich

苯亚硫酸甲酯

98%

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About This Item

线性分子式:
C6H5S(O)OCH3
CAS号:
分子量:
156.20
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:

化驗

98%

折射率

n20/D 1.546 (lit.)

bp

79-83 °C/0.3 mmHg (lit.)

密度

1.194 g/mL at 25 °C (lit.)

λmax

224 nm

SMILES 字串

COS(=O)c1ccccc1

InChI

1S/C7H8O2S/c1-9-10(8)7-5-3-2-4-6-7/h2-6H,1H3

InChI 密鑰

PSNSVDSRLUYDKF-UHFFFAOYSA-N

一般說明

Methyl benzenesulfinate is an ester of aromatic sulfinic acid. It reacts smoothly with thionyl chloride at room temperature to afford sulfinyl chloride and methyl chlorosulfonate.

應用

Methyl benzenesulfinate may be employed for the synthesis of symmetrical disulfides.

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

197.6 °F - closed cup

閃點(°C)

92 °C - closed cup


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Reductive formation of disulfides from sulfenyl, sulfinyl, and sulfonyl derivatives using tri-n-propylamine and trichlorosilane.
Chan T-H, et al.
Journal of the American Chemical Society, 92(24), 7224-7225 (1970)
Derivatives of Aromatic Sulfinic Acids. II. The Reaction of Thionyl Chloride with Sulfinic Esters1, 2.
Herbrandson HF, et al.
Journal of the American Chemical Society, 78(11), 2576-2578 (1956)
Metathetical Reactions of Silver Salts in Solution. II. The Synthesis of Alkyl Sulfonates1.
Emmons WD and Ferris AF.
Journal of the American Chemical Society, 75(5), 2257-2257 (1953)

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