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Merck

459135

Sigma-Aldrich

四甲基氟化铵

97%

别名:

TMAF

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About This Item

线性分子式:
(CH3)4NF
CAS号:
分子量:
93.14
EC號碼:
MDL號碼:
分類程式碼代碼:
12352116
PubChem物質ID:
NACRES:
NA.22

化驗

97%

形狀

solid

mp

170 °C (dec.) (lit.)

SMILES 字串

[F-].C[N+](C)(C)C

InChI

1S/C4H12N.FH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1

InChI 密鑰

GTDKXDWWMOMSFL-UHFFFAOYSA-M

應用

作为如下过程的反应物:
  • 卤化物诱导的2-取代氮丙啶鎓盐开环
  • 通过氟代脱氢反应合成氟代芳烃
  • 通过卤代交换氟化法在离子液体中合成七氟醚
  • 氟化聚(氧钼酸盐)的合成
可用于卤素交换。
四甲基氟化铵可以与硫酰氟组合使用,以用于将芳基酚转化为芳基氟化物。它可以与氨基硅烷反应,从而原位产生鎓酰胺碱,该产物可使杂芳烃去质子化。

象形圖

Exclamation mark

訊號詞

Warning

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Nucleophilic deoxyfluorination of phenols via aryl Fluorosulfonate intermediates.
Schimler SD, et al.
Journal of the American Chemical Society, 139(4), 1452-1455 (2017)
Use of tetramethylammonium fluoride (TMAF) and alkali metal alkoxides as an activator for catalytic deprotonative functionalization of heteroaromatic C (sp2)?H bonds.
Inamoto K, et al.
Tetrahedron, 70(43), 7917-7922 (2014)
Martin-Louis Y Riu et al.
Science advances, 6(13), eaaz3168-eaaz3168 (2020-04-02)
This exploratory synthesis investigation was undertaken to determine the viability of replacing a single carbon vertex with another p-block element in a highly strained tetrahedrane molecule. Phosphorus was selected for this purpose because the stable molecular form of elemental phosphorus
Yasuyuki Ishida et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 27(10), 1053-1056 (2011-10-12)
Thermochemolysis-gas chromatography in the presence of tetramethylammonium acetate was applied to the direct determination of terephthalic acid (TPA) contained in solid decomposition products obtained from the hydrothermal recycling process of poly(ethylene terephthalate) (PET). On the chromatograms of the hydrothermal decomposition
Hui Chong et al.
Langmuir : the ACS journal of surfaces and colloids, 28(4), 2091-2098 (2011-11-08)
A new water-soluble conjugated polymer containing fluorene and boron-dipyrromethene repeat units in the backbones (PBF) that exhibits red emission was synthesized and characterized. Cationic PBF forms uniform nanoparticles with negatively charged disodium salt 3,3'-dithiodipropionic acid (SDPA) in aqueous solution through

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