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Merck
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文件

429120

Sigma-Aldrich

3-甲氧基溴苄

98%

别名:

1-溴甲基-3-甲氧基苯

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About This Item

线性分子式:
CH3OC6H4CH2Br
CAS号:
874-98-6
分子量:
201.06
MDL號碼:
MFCD00216590
分類程式碼代碼:
12352100
PubChem物質ID:
24866839
NACRES:
NA.22

化驗

98%

形狀

liquid

折射率

n20/D 1.575 (lit.)

bp

152 °C (lit.)

密度

1.436 g/mL at 25 °C (lit.)

SMILES 字串

COc1cccc(CBr)c1

InChI

1S/C8H9BrO/c1-10-8-4-2-3-7(5-8)6-9/h2-5H,6H2,1H3

InChI 密鑰

ZKSOJQDNSNJIQW-UHFFFAOYSA-N

相关类别

一般說明

3-甲氧基苄基溴是一种苄基溴衍生物。

應用

3-甲氧基苄基溴（1-溴甲基-3-甲氧基苯）可用于手性琥珀酸衍生物的邻位二价阴离子的非对映选择性烷基化。
它可用于合成以下物质：
  • 6-(3-甲氧基苯基)-己烷-2,4-二酮
  • N-(3-甲氧基苄基)-N-(1-甲基-1-苯乙基)-胺
  • 2-(3-甲氧基苄基)-3-[(1R)-7,7-二甲基-2-氧代双环[2.2.1]庚-1-基]-(3S)-2-硫代双环[2.2.1]-庚烷四氟硼酸盐
  • 1-(3-甲氧基苄基)-5-(1-甲基-1H-咪唑-5-基)-1H-1,2,3-三唑

象形圖

Corrosion
GHS05

訊號詞

Danger

危險聲明

H314

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

235.4 °F - closed cup

閃點（°C）

113 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Application of sulfur ylide mediated epoxidations in the asymmetric synthesis of ?-hydroxy-d-lactones. Synthesis of a mevinic acid analogue and (+)-prelactone B.
Aggarwal VK, et al.
Tetrahedron Asymmetry, 60(43), 9725-9733 (2004)
Synthesis of (-)-kainic acid using chiral lithium amides in an asymmetric dearomatizing cyclization.
Clayden J, et al.
Tetrahedron, 58(23), 4727-4733 (2002)
Highly diastereoselective alkylation of vicinal dianions of chiral succinic acid derivatives: a new general strategy to (R)-?-arylmethyl-?-butyrolactones.
Pohmakotr M, et al.
Tetrahedron Letters, 45(22), 4315-4318 (2004)
Yang Zhang et al.
The Journal of organic chemistry, 71(12), 4516-4520 (2006-06-06)
A mild protocol for the conversion of beta-ketoesters and beta-diketones to carboxylic acids with use of CAN in CH3CN is described. The method is compatible with a number of functional groups, and can generate carboxylic acids under neutral conditions at
Johan R Johansson et al.
The Journal of organic chemistry, 76(7), 2355-2359 (2011-03-11)
An experimentally simple sequential one-pot RuAAC reaction, affording 1,5-disubstituted 1H-1,2,3-triazoles in good to excellent yields starting from an alkyl halide, sodium azide, and an alkyne, is reported. The organic azide is formed in situ by treating the primary alkyl halide
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