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About This Item
线性分子式:
ICH=CHCO2C2H5
CAS号:
分子量:
226.01
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
推荐产品
化驗
98%
形狀
liquid
折射率
n20/D 1.533 (lit.)
bp
85 °C/20 mmHg (lit.)
密度
1.765 g/mL at 25 °C (lit.)
儲存溫度
2-8°C
SMILES 字串
[H]\C(I)=C(/[H])C(=O)OCC
InChI
1S/C5H7IO2/c1-2-8-5(7)3-4-6/h3-4H,2H2,1H3/b4-3-
InChI 密鑰
AELYFQSZXFFNGP-ARJAWSKDSA-N
一般說明
Ethyl cis-3-iodoacrylate (cis-ethyl-β-iodoacrylate, ethyl (Z)-β-iodoacrylate) is Z-vinyl iodide derivative. It is reported to be prepared from ethyl propiolate by treating with sodium iodide. Its Suzuki coupling reaction with cyclic vinyl boronic acids has been studied.
應用
Ethyl cis-3-iodoacrylate may be used in the synthesis of the following:
- vinyl sulfides
- (Z)-1-iodohept-1-en-3-ol
- (E)-1-iodohept-1-en-3-ol
- (Z)-β-iodoacrolein
- 6-oxo-M1Guo
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
210.2 °F - closed cup
閃點（°C）
99 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Stereo-and regiospecific Cu-catalyzed cross-coupling reaction of vinyl iodides and thiols: a very mild and general route for the synthesis of vinyl sulfides.
Kabir MS, et al.
Organic Letters, 10(15), 3363-3366 (2008)
Regiochemical control in the metal-catalyzed transposition of allylic silyl ethers.
Hansen EC and Lee D.
Journal of the American Chemical Society, 128(25), 8142-8143 (2006)
Selection of monoclonal antibodies against 6-oxo-M1dG and their use in an LC-MS/MS assay for the presence of 6-oxo-M1dG in vivo.
Akingbade D, et al.
Chemical Research in Toxicology, 25(2), 454-461 (2012)
A simple and convenient method for the preparation of (Z)-β-iodoacrolein and of (Z)- or (E)-γ-iodo allylic alcohols: (Z)- and (E)-1-iodohept-1-en-3-ol.
Marek I, et al.
Organic Syntheses, 74, 194-194 (1997)
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