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化驗
95%
形狀
liquid
折射率
n20/D 1.409 (lit.)
bp
112 °C (lit.)
密度
0.939 g/mL at 25 °C (lit.)
SMILES 字串
COC(=O)CC=C
InChI
1S/C5H8O2/c1-3-4-5(6)7-2/h3H,1,4H2,2H3
InChI 密鑰
GITITJADGZYSRL-UHFFFAOYSA-N
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一般說明
3-丁烯酸甲酯是一种烯烃酯。据报道，它经过铁羰基促进异构化得到 α, β-不饱和酯。是 (-) 可卡因闪速真空热分解过程中形成的反应产物之一。报道了 3-丁烯酸甲酯的 H 2 和 CH 4 化学电离质谱。
應用
3-丁烯酸甲酯可用于使用分子间烯烃交叉复分解法合成二肽烯烃等排体。
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Site of protonation in the chemical ionization mass spectra of olefinic methyl esters.
Harrison AX and Ichikawa H.
Org. Mass Spectrom., 15(5), 244-248 (1980)
The flash vacuum thermolysis of (-)-cocaine.
Sisti NJ, et al.
Tetrahedron Letters, 30(44), 5977-5980 (1989)
Kuo-Chen Shih et al.
The Journal of organic chemistry, 61(22), 7784-7792 (1996-11-01)
Ultraviolet photolysis of stoichiometric amounts of methyl oleate and Fe(CO)(5) in hexanes solvent at 0 degrees C gives Fe(CO)(3)(eta(4)-alpha,beta-ester) in which the alpha,beta-unsaturated ester isomer of methyl oleate is stabilized by eta(4)-oxadiene pi coordination of the olefin and ester carbonyl
Melissa M Vasbinder et al.
The Journal of organic chemistry, 67(17), 6240-6242 (2002-08-17)
An approach to the synthesis of dipeptide olefin isosteres using intermolecular olefin cross-metathesis is presented. In particular, a synthesis of the Pro-Gly isostere (1) is reported. Conversion of N-BOC-proline into the corresponding vinyl-substituted carbamate provides the N-terminal cross-metathesis partner (2).
Rachel Chapla et al.
Polymers, 12(12) (2020-12-20)
Local mechanical stiffness influences cell behavior, and thus cell culture scaffolds should approximate the stiffness of the tissue type from which the cells are derived. In synthetic hydrogels, this has been difficult to achieve for very soft tissues such as
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