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About This Item
线性分子式:
(CH3)3SiCH=CHCH2OH
CAS号:
分子量:
130.26
Beilstein:
1902497
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
96%
表单
liquid
杂质
<3.5% 3-trimethylsilyl-1-propanol
折射率
n20/D 1.444 (lit.)
沸点
166-168 °C (lit.)
密度
0.848 g/mL at 25 °C (lit.)
官能团
aldehyde
储存温度
−20°C
SMILES字符串
C[Si](C)(C)C\C=C\O
InChI
1S/C6H14OSi/c1-8(2,3)6-4-5-7/h4-5,7H,6H2,1-3H3/b5-4+
InChI key
JKKTXDCTGMUFBS-SNAWJCMRSA-N
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一般描述
trans-3-(Trimethylsilyl)allyl alcohol is a 3-silyl allyl alcohol.
应用
trans-3-(Trimethylsilyl)allyl alcohol is suitable for use in the preparation of 1-iodo-3-trimethylsilyl-2-propene, via mesylation followed by iodide displacement.
警示用语:
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
136.4 °F - closed cup
闪点(°C)
58 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Minh Pham et al.
The Journal of organic chemistry, 73(2), 741-744 (2007-12-22)
In the presence of indium metal, 3-iodo-2-[(trimethylsilyl)methyl]propene (1) reacts with sequentially added aldehydes to provide cis-2,6-disubstituted tetrahydropyrans in good yields. Evidence suggests that InI, formed upon aldehyde (R1CHO) allylation in aqueous media, acts as a promoter for the silyl-Prins reaction
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