361755

(1,5-环辛二烯)二(三苯基膦)六氟磷酸铑二氯甲烷络合物(1:1)

• 别名: NSC 179445
• 经验公式（希尔记法）: C₄₅H₄₄Cl₂F₆P₃Rh
• CAS号: 35238-97-2
• 分子量: 965.55
• MDL编号: MFCD02091684
• UNSPSC代码: 12352300
• PubChem化学物质编号: 24862254
• NACRES: NA.22

属性

• 反应适用性: core: rhodium; reagent type: catalyst
• mp: 215 °C (lit.)
• SMILES字符串: [Rh+].ClCCl.F[P-](F)(F)(F)(F)F.[CH]1[CH]CC[CH][CH]CC1.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7
• InChI: 1S/2C18H15P.C8H12.CH2Cl2.F6P.Rh/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-6-8-7-5-3-1;2-1-3;1-7(2,3,4,5)6;/h2*1-15H;1-2,7-8H,3-6H2;1H2;;/q;;;;-1;+1/b;;2-1-,8-7-;;;
• InChI key: FCVRPQBVWYQXFH-ISVFTUMHSA-N

说明

应用

Catalyst for:

• Polycyclotrimerization reactions
• Hydrosilylation and hydrogenation reactions
• Hydroformylation reactions
• Regioselective di- and trisilylation reactions
• Mannich and nitro-Mannich reactions
• Reductive alkylation reactions

安全信息

• 象形图: GHS07
• 警示用语：: Warning
• 危险声明: H315,H319,H335
• 预防措施声明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危险分类: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 靶器官: Respiratory system
• 储存分类代码: 11 - Combustible Solids
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable
• 个人防护装备: dust mask type N95 (US), Eyeshields, Gloves