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![[1,1′-双(二苯基膦)二茂铁]二氯化钯(II)](/deepweb/assets/sigmaaldrich/product/structures/130/734/8846aa26-1858-458a-998d-8c306c13bf0f/640/8846aa26-1858-458a-998d-8c306c13bf0f.png)
化驗
97%
形狀
solid
反應適用性
reagent type: ligand
reaction type: C-C Bond Formation
reagent type: ligand
reaction type: Carbonylations
reagent type: ligand
reaction type: Negishi Coupling
reagent type: ligand
reaction type: Sonogashira Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
mp
63-65 °C (lit.)
官能基
phosphine
SMILES 字串
C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4
InChI
1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
InChI 密鑰
LVEYOSJUKRVCCF-UHFFFAOYSA-N
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一般說明
1,3-双（二苯膦基）丙烷是一种有机磷化合物，属于双膦配体。它可用于过渡金属催化的交叉偶联反应，如Suzuki-Miyaura偶联、Sonogashira偶联和Negishi偶联反应。1,3-双（二苯膦基）丙烷也可用于开发生物活性金属配位络合物，因为其可以通过单齿或双齿配体与金属稳定地络合。
應用
- 纳米团簇酶（Nanoclusterzyme ）双重比色传感：该研究探讨了利用1,3-双(二苯基膦基)丙烷进行纳米团簇酶的制备，展示了其在双重比色传感中的应用：该应用表明了其在分析化学和传感器开发中的重大潜力（Zhao et al., 2023）。
- 二十面体单元的组装：该研究详细介绍了利用1,3-双(二苯基膦基)丙烷，更牢固地在金属簇内组装二十面体单元，强调了其在改善结构稳定性的作用以及在纳米技术中的潜在应用（Zhou et al., 2023）。
- 金团簇（gold cluster ）的合成和稳定性：论文重点关注了以1,3-双(二苯基膦基)丙烷合成的混合二膦连接的金团簇及其稳定性评估，强调了其在有机金属化学的关键作用和潜在工业应用（Philliber et al., 2022）。
- 金膦团簇尺寸转换：该研究考察了在1,3-双(二苯基膦基)丙烷的促进下，核心电荷密度对Au(6) P(8) 向Au(8) P(8) Cl(2)转换的的尺寸转换作用，展示了对团簇化学的新见解及其与催化和电学应用的关联性Lv et al., 2020）。
- 供体-受体双嵌段共聚物的合成：该研究在序列聚合中，采用1,3-双(二苯基膦基)丙烷来合成一种新型供体-受体双嵌段共聚物，重点介绍了该配体在聚合物化学中的多功能性及其在先进材料制备中的潜力（Ono et al., 2014）。
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
其他客户在看
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Molecular and cellular biochemistry, 438(1-2), 199-217 (2017-08-11)
The aim of this work was the synthesis, characterization, and cytotoxicity evaluation of three new Ru(II) complexes with a general formula [Ru(Spy)(bipy)(P-P)]PF
Zelinda Engelbrecht et al.
Anti-cancer agents in medicinal chemistry, 18(3), 394-400 (2017-05-23)
A broad range of metal-coordinated complexes have been studied for their anticancer activities. However, some of these complexes display high toxicity profiles to non-malignant cells, therefore limiting their use in cancer therapeutics. Several silver(I) triphenylphosphine adducts were prepared as 1:1
Nathália Cristina Campanella et al.
Genetics and molecular biology, 35(1), 159-163 (2012-04-07)
The antitumorigenic potential of two palladium(II) complexes, [Pd(ca(2)-o-phen)Cl(2)] - C1 and [Pd(dmba)(dppp)Cl] - C2, was evaluated, using MDA-MB-435 cells, a human breast adenocarcinoma cell-line that does not express the estrogen receptor α (ER-). Growth inhibition and induced alterations in cell-morphology
Heyan Jiang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(34), 8280-8285 (2017-03-24)
The effect of chain structure on flexibility and stability of macromolecules containing weak P-Fe metal coordination bonds is studied. Migration insertion polymerization (MIP) of FpC
Renxuan Xie et al.
Nature communications, 11(1), 893-893 (2020-02-16)
The glass transition temperature (Tg) is a key property that dictates the applicability of conjugated polymers. The Tg demarks the transition into a brittle glassy state, making its accurate prediction for conjugated polymers crucial for the design of soft, stretchable
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