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化驗
97%
反應適用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
mp
196 °C (dec.) (lit.)
官能基
phosphine
SMILES 字串
Br.c1ccc(cc1)P(c2ccccc2)c3ccccc3
InChI
1S/C18H15P.BrH/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h1-15H;1H
InChI 密鑰
CMSYDJVRTHCWFP-UHFFFAOYSA-N
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應用
用作无水氢溴酸的温和来源；从叔醇合成 THP 醚的催化剂； 磷盐制备。
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
其他客户在看
Hamanaka, N.; Kosuge, S.; Iguchi, S.
Synlett, 139-139 (1990)
Kaila, N.; Blumenstein, M. et al.
The Journal of Organic Chemistry, 57, 4576-4576 (1992)
Catherine J Smith et al.
Organic & biomolecular chemistry, 9(6), 1927-1937 (2011-02-02)
Here we describe general flow processes for the synthesis of alkyl and aryl azides, and the development of a new monolithic triphenylphosphine reagent, which provides a convenient format for the use of this versatile reagent in flow. The utility of
Su-Zhen Bai et al.
Molecules (Basel, Switzerland), 17(5), 5532-5543 (2012-05-11)
A new triphenylphosphine adduct of cyclopalladated ferrocenylpyridazine containing a chloride anion, 2a, has been synthesized from the reaction of the chloride-bridged palladacyclic dimer 1a with triphenylphosphine. The corresponding adducts 3a,b containing iodide anion have been readily prepared through anion exchange
Jun Hu et al.
Chemical communications (Cambridge, England), 48(91), 11256-11258 (2012-10-17)
In the presence of triphenylphosphine, copper(II) chloride can catalyze an intermolecular ortho-acylation reaction of phenols with aryl aldehydes. The reaction proceeds smoothly with a wide range of starting materials, and furthermore, it can be used to synthesize xanthone derivatives in
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