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品質等級
反應適用性
reaction type: Grignard Reaction
濃度
2.0 M in diethyl ether
密度
0.947 g/mL at 25 °C
SMILES 字串
CCCCC[Mg]Br
InChI
1S/C5H11.BrH.Mg/c1-3-5-4-2;;/h1,3-5H2,2H3;1H;/q;;+1/p-1
InChI 密鑰
ZXWGTPYWPZGZPT-UHFFFAOYSA-M
應用
Pentylmagnesium bromide solution is a Grignard reagent that can be used in the preparation of:
It can also be used as a reagent to synthesize a key intermediate by olefin alkylation in the total synthesis of alkaloid, (+)-hyperaspine , and surface alkylation of H-terminated Si (111), by Si-C bond formation.
- Alkanes via Ni or Cu-catalyzed cross-coupling reaction with alkyl fluorides.
- Hydroxypiperidinones via the addition-cyclization-deprotection process of aldimines.
It can also be used as a reagent to synthesize a key intermediate by olefin alkylation in the total synthesis of alkaloid, (+)-hyperaspine , and surface alkylation of H-terminated Si (111), by Si-C bond formation.
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
標靶器官
Central nervous system
安全危害
儲存類別代碼
4.3 - Hazardous materials which set free flammable gases upon contact with water
水污染物質分類（WGK）
WGK 3
閃點（°F）
-40.0 °F - closed cup
閃點（°C）
-40 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
其他客户在看
A six-step asymmetric synthesis of (+)-hyperaspine
Comins DL and Sahn JJ
Organic Letters, 7(23), 5227-5228 (2005)
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Diastereoconvergent Synthesis of trans-5-Hydroxy-6-Substituted-2-Piperidinones by Addition-Cyclization-Deprotection Process
Si Chang-Mei, et al.
Organic Letters, 16(16), 4328-4331 (2014)
Ni-or Cu-catalyzed cross-coupling reaction of alkyl fluorides with Grignard reagents
Terao J, et al.
Journal of the American Chemical Society, 125(19), 5646-5647 (2003)
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