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品質等級
反應適用性
reaction type: Grignard Reaction
濃度
3.0 M in diethyl ether
密度
1.02 g/mL at 25 °C
SMILES 字串
CC[Mg]Br
InChI
1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1
InChI 密鑰
TWTWFMUQSOFTRN-UHFFFAOYSA-M
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一般說明
乙基溴化镁是一种有机镁化合物,俗称格氏试剂。它是一种功能强大的碳亲核试剂,主要用于 C-C 键的形成。
應用
乙基溴化镁溶液(3.0 M,乙醚中)可用于铜 (I) 催化的烯丙基取代反应。
法律資訊
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1
標靶器官
Respiratory system
安全危害
儲存類別代碼
4.3 - Hazardous materials which set free flammable gases upon contact with water
水污染物質分類(WGK)
WGK 1
閃點(°F)
-40.0 °F - closed cup
閃點(°C)
-40 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
其他客户在看
Enantioselective Copper-Catalyzed SN2? Substitution with Grignard Reagents.
Synlett, 0927-0930 (2001)
Organic Chemistry, 542-542 (2008)
Organic & biomolecular chemistry, 2(10), 1447-1455 (2004-05-12)
Copper mediated allylic substitutions and conjugate additions to geranyl, cinnamyl and allylic indole compounds have been investigated with the aim of finding a method for the creation of the all-carbon quaternary centre present in the natural product lyngbyatoxin A. Reaction
Chemical & pharmaceutical bulletin, 48(12), 1999-2002 (2001-01-06)
The direct alpha-bromination of various ketones using trifluoromethanesulfonic anhydride and Grignard reagent or magnesium bromide in ether gave the corresponding alpha-bromo ketones in moderate to good yields under mild reaction conditions.
Lipids, 37(8), 817-821 (2002-10-10)
An analytical procedure was developed for regiodistribution analysis of TAG using alpha-MAG prepared by an ethyl magnesium bromide deacylation. In the present communication, the deacylation procedure is shown to lead to representative alpha-MAG, allowing the composition of the native TAG
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