所有图片(3)
About This Item
线性分子式:
NaOC(CH3)2CH2CH3
CAS号:
分子量:
110.13
Beilstein:
3983987
EC 号:
MDL编号:
UNSPSC代码:
12352001
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
95%
SMILES字符串
[Na+].CCC(C)(C)[O-]
InChI
1S/C5H11O.Na/c1-4-5(2,3)6;/h4H2,1-3H3;/q-1;+1
InChI key
CGRKYEALWSRNJS-UHFFFAOYSA-N
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应用
钠 叔 -五氧化物 (NaO t -Am) 是醇类 和仲胺 N -氰化反应中常用的碱。也可用于制备络合还原剂,将 1-卤萘和取代卤苯还原为相应的的萘和苯。
警示用语:
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Sol. 1 - Self-heat. 1 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 1
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Activation of reducing agents: Sodium hydride-containing ?complex reducing agents?: I. Reduction of aromatic halides.
Guillaumet G, et al.
Journal of Organometallic Chemistry, 92(1), 43-47 (1975)
Brandon K Tate et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(28), 10160-10169 (2015-06-11)
Alkoxide-bridged disilver cations react with dihydrogen to form hydride-bridged cations, releasing free alcohol. Hydrogenolysis of neutral silver fluorides affords hydride-bridged disilver cations as their bifluoride salts. These reactions proceed most efficiently when the supporting ligands are expanded N-heterocyclic carbenes (NHCs)
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