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化驗
97%
形狀
chunks
mp
137-140 °C (lit.)
SMILES 字串
ClC(Cl)(Cl)S(Cl)(=O)=O
InChI
1S/CCl4O2S/c2-1(3,4)8(5,6)7
InChI 密鑰
ZCPSWAFANXCCOT-UHFFFAOYSA-N
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一般說明
Trichloromethanesulfonyl chloride is an efficient free radical chlorinating agent. It reacts with pent-4-enylcobaloximes in inert solvent under tugsten lamp irradiation to yield 2-(β,β,β- trichloroethyl)sulfolanes. It also reacts with trimethylsilyl enol ethers of acetophenones in the presence of a ruthenium (II) phosphine complex to yield 1-aryl-3,3-dichloropropen-1-one and α-chloroacetophenones.
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
其他客户在看
Reactions of trichloromethanesulfonyl chloride and carbon tetrachloride with silyl enol ethers catalyzed by a ruthenium (II) phosphine complex.
Kamigata N, et al.
Journal of Organometallic Chemistry, 552(1), 9-43 (1998)
TRICHLOROMETHANESULFONYL CHLORIDE AS A SELECTIVE CHLORINATING AGENT1.
Huyser ES.
Journal of the American Chemical Society, 82(19), 5246-5247 (1960)
Homolytic displacement at saturated carbon. Part 9. The reactions of trichloromethanesulfonyl chloride with pent-4-enylcobaloximes and with olefins. A novel route to (trichloroethyl) sulfolanes via an SHi mechanism.
Ashcroft MR, et al.
The Journal of Organic Chemistry, 49(10), 1751-1761 (1984)
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