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Merck
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文件

224367

Sigma-Aldrich

双(三甲基硅基)氨基锂 溶液

1.0 M in hexanes

别名:

六甲基二硅氮烷 锂盐

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About This Item

线性分子式:
[(CH3)3Si]2NLi
CAS号:
4039-32-1
分子量:
167.33
Beilstein:
3567910
MDL號碼:
MFCD00008261
分類程式碼代碼:
12352111
PubChem物質ID:
24853431
NACRES:
NA.22

形狀

liquid

品質等級

100

濃度

1.0 M in hexanes

bp

55-56 °C

密度

0.707 g/mL at 25 °C

SMILES 字串

[Li]N([Si](C)(C)C)[Si](C)(C)C

InChI

1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1

InChI 密鑰

YNESATAKKCNGOF-UHFFFAOYSA-N

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應用

与铑(I)催化共同作用可显著加快苯乙炔的聚合反应。

包裝

查看可回收的容器产品。

訊號詞

Danger

危險分類

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Self-heat. 1 - Skin Corr. 1B - STOT RE 2 Inhalation - STOT SE 3

標靶器官

Central nervous system, Nervous system

安全危害

EUH014

儲存類別代碼

4.2 - Pyrophoric and self-heating hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

-23.8 °F - closed cup

閃點（°C）

-31 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles

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Macromolecules, 39, 5347-5347 (2006)
Elsa Vennat et al.
Dental materials : official publication of the Academy of Dental Materials, 25(6), 729-735 (2009-01-29)
The objectives of this study were to assess demineralized dentin porosity and quantify the different porous features distribution within the material using mercury intrusion porosimetry (MIP) technique. We compared hexamethyldisilazane (HMDS) drying and lyophilization (LYO) (freeze-drying) in sample preparation. Fifty-six
Nur Hazlin Hazrin-Chong et al.
Journal of microbiological methods, 90(2), 96-99 (2012-05-09)
The use of hexamethyldisilazane (HMDS) as a drying agent was investigated in the specimen preparation for scanning electron microscopy (SEM) imaging of bacterial surface colonization on sub-bituminous coal. The ability of microbes to biofragment, ferment and generate methane from coal
Nan Li et al.
Lab on a chip, 8(12), 2105-2112 (2008-11-22)
High-density live cell array serves as a valuable tool for the development of high-throughput immunophenotyping systems and cell-based biosensors. In this paper, we have, for the first time, demonstrated a simple fabrication process to form the hexamethyldisilazane (HMDS) and poly(ethylene
Mario Janjetovic et al.
Chemical communications (Cambridge, England), 49(18), 1826-1828 (2013-01-30)
Sm(HMDS)(2) in n-hexane mediates fast cleavage of primary, secondary and tertiary alkyl fluorides in good to excellent yields. In n-hexane Sm(HMDS)(2) exhibits uniquely enhanced reductive ability towards the C-F bond compared to when using THF as solvent.
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