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蒸汽壓力
1.75 mmHg ( 25 °C)
131 mmHg ( 250 °C)
品質等級
化驗
95%
形狀
powder
反應適用性
reagent type: catalyst
core: molybdenum
雜質
<0.5% insoluble matter
bp
268 °C (lit.)
mp
194 °C (lit.)
密度
2.928 g/mL at 25 °C (lit.)
應用
battery manufacturing
SMILES 字串
Cl[Mo](Cl)(Cl)(Cl)Cl
InChI
1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5
InChI 密鑰
GICWIDZXWJGTCI-UHFFFAOYSA-I
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一般說明
氯化钼(V)是一种路易斯酸,被广泛用作许多有机反应的催化剂和试剂。它可以由钼金属的直接氯化或亚硫酰氯和 MoO3的加热回流制备。
應用
氯化钼(V)可用作以下反应的高效催化剂:
它也可用作合成氧化铝/钼纳米复合材料和亚甲基钼试剂的前体,用于化学选择性羰基烯化反应。
- 硝基苯和醇的缩合以及烯基锂试剂的C-C偶联。
- 苄基醇与磺胺和氨基甲酸酯的直接酰胺化反应。
它也可用作合成氧化铝/钼纳米复合材料和亚甲基钼试剂的前体,用于化学选择性羰基烯化反应。
訊號詞
Danger
危險聲明
危險分類
Carc. 2 - Eye Dam. 1 - Skin Corr. 1B
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
其他客户在看
Organic letters, 13(5), 916-919 (2011-02-02)
A domino sequence involving various MoCl(5)-mediated oxidations followed by trapping and supposed [3,3]-sigmatropic rearrangement provides a fast access to the full carbon skeleton of metasequirin-B. A variety of different moieties R(1) and R(2) are tolerated.
Chemical Communications (Cambridge, England), 1615-1615 (1997)
Bioorganic & medicinal chemistry letters, 22(11), 3676-3681 (2012-05-02)
Mo(VI) and Mo(V) salts both react selectively with Hantzsch esters to produce substitute pyridines in good-to-excellent yield (75-99%). The remarkable reactivity and selectivity of MoOCl(4) under reflux of acetonitrile and MoCl(5) in dichloromethane at room temperature encouraged us to propose
Mutation research, 320(1-2), 133-140 (1994-01-01)
A series of metal chlorides were subjected to the wing spot test of Drosophila melanogaster. In the test, larvae trans-heterozygous for the wing-hair mutations mwh and flr were orally treated at the third instar stage with a test compound and
Organic letters, 14(12), 2976-2979 (2012-06-05)
The strong oxidative power of molybdenum pentachloride gives rise to an efficient oxidative C-C bond formation of benzil derivatives to the corresponding 9,10-phenanthrenequinones. A highly complementary method to previous approaches was developed. The required derivatives are accessible in a modular
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