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蒸汽密度
2.4 (vs air)
蒸汽壓力
121 mmHg ( 20 °C)
13.44 psi ( 55 °C)
5.35 psi ( 20 °C)
化驗
95%
形狀
liquid
折射率
n20/D 1.416 (lit.)
bp
68-70 °C (lit.)
mp
−81 °C (lit.)
密度
0.85 g/mL at 25 °C (lit.)
儲存溫度
2-8°C
SMILES 字串
[H]C(=O)C(C)=C
InChI
1S/C4H6O/c1-4(2)3-5/h3H,1H2,2H3
InChI 密鑰
STNJBCKSHOAVAJ-UHFFFAOYSA-N
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一般說明
甲基丙烯醛在300℃下在杂多酸催化剂(主要是 12-钼磷酸)催化下氧化生成甲基丙烯酸 。它是异戊二烯氧化的主要产物 。
應用
甲基丙烯醛用于研究烃氧化产物和萜烯氧化产物甲基丙烯醛对人眨眼频率的影响,影响水平在十亿分之几。它还用于测定氯原子与丙烯醛、甲基丙烯醛和甲基乙烯基酮反应的速率常数和产物 。
訊號詞
Danger
危險分類
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Muta. 2 - Skin Corr. 1B
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
5.0 °F - closed cup
閃點(°C)
-15 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
其他客户在看
Journal of the American Chemical Society, 127(38), 13386-13398 (2005-09-22)
The rhodium and iridium Lewis-acid cations [(eta(5)-C(5)Me(5))M{(R)-Prophos}(H(2)O)](2+) ((R)-Prophos = 1,2-bis(diphenylphosphino)propane) efficiently catalyze the enantioselective 1,3-dipolar cycloaddition of nitrones to methacrolein. Reactions occur with perfect endo selectivity and with enantiomeric excesses up to 96%. Intermediates [(eta(5)-C(5)Me(5))M{(R)-Prophos}(methacrolein)](SbF(6))(2) (M = Rh (3), Ir
Isoprene and its oxidation products methyl vinyl ketone, methacrolein, and isoprene related peroxides measured online over the tropical rain forest of Surinam in March 1998.
Journal of Atmospheric Chemistry, 38(2), 167-185 (2001)
The journal of physical chemistry. A, 116(24), 5763-5768 (2012-03-29)
We investigate the oxidation of methacryloylperoxy nitrate (MPAN) and methacrylicperoxy acid (MPAA) by the hydroxyl radical (OH) theoretically, using both density functional theory [B3LYP] and explicitly correlated coupled cluster theory [CCSD(T)-F12]. These two compounds are produced following the abstraction of
The Journal of organic chemistry, 74(2), 861-868 (2008-12-11)
The cationic oxazaborolidine-catalyzed Diels-Alder reactions of butadiene and a series of five dienophiles have been studied using density functional theory (B3LYP/6-31G(d)). In each case, the computational results successfully reproduce the experimentally observed sense of stereoinduction and enantiomeric ratio. The computed
Toxicology letters, 114(1-3), 197-202 (2000-03-14)
The acute respiratory effects of airborne exposure to methacrolein were studied in a recent refinement of the standard test method with mice (ASTM, 1984. American Society for Testing and Materials, Philadelphia). Irritation of the upper respiratory tract caused a concentration-dependent
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