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Merck

116025

Sigma-Aldrich

扁桃腈

technical grade

别名:

α-氰基苄醇, 杏仁腈, 苯甲氰醇

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About This Item

线性分子式:
C6H5CH(OH)CN
CAS号:
分子量:
133.15
Beilstein:
2207122
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

等級

technical grade

折射率

n20/D 1.530 (lit.)

bp

170 °C (lit.)

溶解度

alcohol: freely soluble
chloroform: freely soluble
diethyl ether: freely soluble

密度

1.117 g/mL at 25 °C (lit.)

SMILES 字串

OC(C#N)c1ccccc1

InChI

1S/C8H7NO/c9-6-8(10)7-4-2-1-3-5-7/h1-5,8,10H

InChI 密鑰

NNICRUQPODTGRU-UHFFFAOYSA-N

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應用

Mandelonitrile has been used to extract mandeloamide by the nitrilase variants.

象形圖

Skull and crossbonesCorrosion

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

206.6 °F - closed cup

閃點(°C)

97 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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D H Sreenivasa Rao et al.
Applied biochemistry and biotechnology, 193(2), 560-576 (2020-10-13)
Enantiopure β-nitroalcohols are versatile intermediates used in the synthesis of important pharmaceuticals and chiral synthons. In this article, immobilized Arabidopsis thaliana HNL (AtHNL)-catalyzed preparation of (S)-β-nitroalcohols from their racemic mixtures via retro-Henry reaction was studied. AtHNL used in biocatalysis was
A biocatalytic Henry reaction--the hydroxynitrile lyase from Hevea brasiliensis also catalyzes nitroaldol reactions.
Thomas Purkarthofer et al.
Angewandte Chemie (International ed. in English), 45(21), 3454-3456 (2006-04-25)
Diana Uhrich et al.
Frontiers in microbiology, 8, 2111-2111 (2017-11-25)
The preparation and characterization of UV-cured polyurethane-based materials for the mild inclusion immobilization of enzymes was investigated. Full curing of the polymer precursor/enzyme solution mixture was realized by a short irradiation with UV-light at ambient temperatures. The included aqueous enzyme
Aem Nuylert et al.
Chembiochem : a European journal of chemical biology, 18(3), 257-265 (2016-12-04)
A hydroxynitrile lyase from the passion fruit Passiflora edulis (PeHNL) was isolated from the leaves and showed high stability in biphasic co-organic solvent systems for cyanohydrin synthesis. Cyanohydrins are important building blocks for the production of fine chemicals and pharmaceuticals.
Zhi-Jun Zhang et al.
Bioprocess and biosystems engineering, 34(3), 315-322 (2010-10-21)
A nitrilase gene from Alcaligenes sp. ECU0401 was cloned and overexpressed in Escherichia coli BL21 (DE3) in a soluble form. The encoded protein with a His₆-tag was purified to nearly homogeneity as revealed by SDS-PAGE with a molecular weight of

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