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Merck
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115150

Sigma-Aldrich

硫光气

别名:

硫羰化二氯

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About This Item

线性分子式:
CSCl2
CAS号:
463-71-8
分子量:
114.98
Beilstein:
1633495
EC 号:
207-341-6
MDL编号:
MFCD00004918
UNSPSC代码:
12352000
eCl@ss:
38020402
PubChem化学物质编号:
24847201
NACRES:
NA.22

蒸汽密度

4 (vs air)

质量水平

200

反应适用性

reaction type: Carbonylations

折射率

n20/D 1.548 (lit.)

沸点

70-75 °C (lit.)

密度

1.50 g/mL at 20 °C (lit.)

官能团

chloro

储存温度

2-8°C

SMILES字符串

ClC(Cl)=S

InChI

1S/CCl2S/c2-1(3)4

InChI key

ZWZVWGITAAIFPS-UHFFFAOYSA-N

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应用

制备大硫脲配体，以用于将醇经钯催化的需氧氧化反应氧化成醛和酮。

象形图

Skull and crossbonesCorrosion
GHS06,GHS05

警示用语：

Danger

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
STBJ7925
STBH8658
STBH9037
STBH9036
STBH8659

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Christof Jung et al.
The journal of physical chemistry. A, 110(16), 5317-5325 (2006-04-21)
The dispersed fluorescence spectrum of the ground electronic state of thiophosgene, SCCl2, is analyzed in a very complex region of vibrational excitation, 7000-9000 cm(-1). The final result is that most of the inferred excited vibrational levels are assigned in terms
Cheng Li et al.
Colloids and surfaces. B, Biointerfaces, 171, 159-166 (2018-07-22)
Dual mode imaging technology is widely developed to achieve the early-stage precision cancer diagnosis. Here we designed a dual-modal magnetic resonance/near infrared fluorescence optical imaging contrast agent (GdF-SS-NIR783) with the fluorescence activatable and safer gadofullerene. The nanoprobes were fabricated by
W Kedzierski et al.
The Journal of chemical physics, 120(19), 9087-9089 (2004-07-23)
A special xenon matrix detector has been used to study the production of S(1S) following controlled electron impact on thiophosgene (Cl2CS) targets over an electron energy range from threshold to 400 eV. Time-of-flight spectroscopy has been used to measure S(1S)
Youlia Hagooly et al.
The Journal of organic chemistry, 73(17), 6780-6783 (2008-08-13)
A general preparation for aromatic and aliphatic, cyclic as well as linear, symmetric and asymmetric difluoromethylenedioxy derivatives is described. The alcohols were reacted with thiophosgene to give thiocarbonates, which in turn were reacted with BrF3. The fluorination step is complete
Synlett, 3057-3057 (2006)
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