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Merck

109533

Sigma-Aldrich

衣康酸二甲酯

97%

别名:

2-(Methylene)butanedioic dimethyl ester

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About This Item

线性分子式:
CH3O2CCH2C(=CH2)CO2CH3
CAS号:
分子量:
158.15
Beilstein:
386674
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

97%

形狀

solid

bp

208 °C (lit.)

mp

37-41 °C (lit.)

密度

1.124 g/mL at 25 °C (lit.)

SMILES 字串

COC(=O)CC(=C)C(=O)OC

InChI

1S/C7H10O4/c1-5(7(9)11-3)4-6(8)10-2/h1,4H2,2-3H3

InChI 密鑰

ZWWQRMFIZFPUAA-UHFFFAOYSA-N

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一般說明

衣康酸二甲酯在Rh(I)催化下进行对映选择性加氢反应,在(1,2-二芳基膦基氧基)环己烷的芳环上选择适当的取代基可提高反应的活性。.

應用

衣康酸二甲酯可用于全同立构聚(丙烯)的官能化。它可用于聚酯:聚(异山梨醇衣康酸酯)和聚(异山梨醇衣康酸酯-共-琥珀酸酯)的交联

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Skin Irrit. 2 - Skin Sens. 1B

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

212.0 °F - closed cup

閃點(°C)

100 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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Modification of poly (propylene) through grafting with dimethyl itaconate in solution.
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T. V. RajanBabu et al.
The Journal of organic chemistry, 64(10), 3429-3447 (2001-10-25)
Enantioselectivity of Rh(I)-catalyzed asymmetric hydrogenation of dehydroamino acid derivatives and dimethyl itaconate can be enhanced by the appropriate choice of substituents on the aromatic rings of vicinal diarylphosphinites derived from carbohydrates as well as trans-cyclohexane-1,2-diol. For example, the use of
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