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Merck

109223

Sigma-Aldrich

1-溴金刚烷

99%

别名:

1-溴代金刚烷

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About This Item

经验公式(希尔记法):
C10H15Br
CAS号:
分子量:
215.13
Beilstein:
1098857
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

99%

mp

116-118 °C (lit.)

SMILES 字串

BrC12C[C@H]3C[C@H](C[C@H](C3)C1)C2

InChI

1S/C10H15Br/c11-10-4-7-1-8(5-10)3-9(2-7)6-10/h7-9H,1-6H2/t7-,8+,9-,10-

InChI 密鑰

VQHPRVYDKRESCL-CHIWXEEVSA-N

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一般說明

1-溴金刚烷可与α-、β-,以及γ-环糊精形成包合络合物。它会引起β-二酮的Co(II)络合物的烷基化

應用

1-溴金刚烷被用于合成新的有机-有机纳米级复合薄膜电介质

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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P. M. Ivanov et al.
The Journal of organic chemistry, 61(20), 7012-7017 (1996-10-04)
The inclusion complexes between the most commonly used cyclodextrins (alpha-, beta-, and gamma-CD) and 1-bromoadamantane were prepared and studied experimentally by NMR methods and by molecular dynamics simulations (AMBER force field) with solvation. The NMR results suggest host/guest ratios of
Alkylation of ?-diketones through their co (II), co (III) and zn (II) complexes. 1-Bromoadamantane as alkylating agent.
Gonzalez A, et al.
Tetrahedron Letters, 26(31), 3735-3738 (1985)
Jitendra N Tiwari et al.
ChemSusChem, 3(9), 1051-1056 (2010-07-14)
A new organic-organic nanoscale composite thin-film (NCTF) dielectric has been synthesized by solution deposition of 1-bromoadamantane and triblock copolymer (Pluronic P123, BASF, EO20-PO70-EO20), in which the precursor solution has been achieved with organic additives. We have used a sol-gel process
Cheng Li et al.
Analytica chimica acta, 1066, 121-130 (2019-04-28)
A visual, rapid, and sensitive method for the detection of two algal metabolites, geosmin (GSM) and 2-methylisoborneol (2-MIB) using a competitive displacement technique based on molecular imprinted polymers (MIPs) and fluorescent tags was developed. In this method, fluorescent tags that

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