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Merck

244767

Sigma-Aldrich

Lithium tetrafluoroborate

greener alternative

98%

Sinónimos:

Lithium borofluoride, Lithium fluoroborate

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10 G
64,90 €
50 G
254,00 €

64,90 €


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10 G
64,90 €
50 G
254,00 €

About This Item

Fórmula lineal:
LiBF4
Número de CAS:
Peso molecular:
93.75
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de la sustancia en PubChem:
NACRES:
NA.23

64,90 €


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Ensayo

98%

Formulario

powder

características de los productos alternativos más sostenibles

Design for Energy Efficiency
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sustainability

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mp

293-300 °C (dec.) (lit.)

categoría alternativa más sostenible

cadena SMILES

[Li+].F[B-](F)(F)F

InChI

1S/BF4.Li/c2-1(3,4)5;/q-1;+1

Clave InChI

UFXJWFBILHTTET-UHFFFAOYSA-N

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Descripción general

Lithium tetrafluoroborate (LiBF₄) is a versatile compound with significant applications in research, particularly in the fields of battery technology, solid-state batteries, supercapacitors, electrochemical sensors, catalysis, electrolyte development, polymer electrolytes, and environmental studies.

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Aplicación

Lithium tetrafluoroborate (LiBF₄) is used as an electrolyte salt in lithium-ion batteries. It contributes to the overall ionic conductivity of the electrolyte and helps in achieving better battery performance. LiBF₄ is used as an electrolyte additive in supercapacitors to enhance their performance, particularly in terms of energy density and charge-discharge cycles. It can be used as a catalyst in various chemical reactions. Its properties can help improve the efficiency and selectivity of catalytic processes. In a study, it was reported that lithium tetrafluoroborate can serve as an efficient catalyst for the intermolecular aza-Michael addition of aromatic amines to electron-deficient alkenes. The suitability of this catalyst for intramolecular aza-Michael addition, resulting in the formation of 2-aryl-2,3-dihydroquinolin-4(1H)-ones, was also described. Lithium tetrafluoroborate is a mild Lewis acid for Diels-Alder reactions. It is used as a catalyst for mild and efficient aminolysis of oxiranes.[1][2][3][4]

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Acute Tox. 4 Oral - Eye Dam. 1 - Muta. 2 - Skin Corr. 1B

Código de clase de almacenamiento

8B - Non-combustible corrosive hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Certificados de análisis (COA)

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Visite la Librería de documentos

Tetrahedron Letters, 32, 1549-1549 (1991)
Tetrahedron Letters, 31, 4661-4661 (1990)
Lithium tetrafluoroborate as an electrolyte additive to improve the high voltage performance of lithium-ion battery.
Zuo X, et al.
Journal of the Electrochemical Society, 160(8), A1199-A1204 (2013)
Takahiro Ichikawa et al.
Journal of the American Chemical Society, 133(7), 2163-2169 (2011-01-29)
Thermotropic bicontinuous cubic (Cub(bi)) liquid-crystalline (LC) compounds based on a polymerizable ammonium moiety complexed with a lithium salt have been designed to obtain lithium ion-conductive all solid polymeric films having 3D interconnected ionic channels. The monomer shows a Cub(bi) phase
J S Yadav et al.
Carbohydrate research, 332(2), 221-224 (2001-07-04)
The treatment of glycals with allyltrimethylsilane in the presence of lithium tetrafluoroborate in acetonitrile gave the corresponding allyl 2,3-unsaturated C-glycosylic compounds in excellent yields with high anomeric selectivity.

Preguntas

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 respuesta
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 respuesta
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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