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Merck

774138

Sigma-Aldrich

Lithium difluoro(oxalato)borate

greener alternative

Sinónimos:

LIDFOB, LIF2OB, LIFOB, LIODFB, Lithium difluoro(ethanedioato)borate, Lithium oxalatodigluoroborate

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About This Item

Fórmula lineal:
LiBF2(C2O4)
Número de CAS:
Peso molecular:
143.77
Número MDL:
Código UNSPSC:
26111700
ID de la sustancia en PubChem:
NACRES:
NA.23

formulario

powder

Nivel de calidad

características de los productos alternativos más sostenibles

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

265-271 °C

aplicaciones

battery manufacturing

categoría alternativa más sostenible

cadena SMILES

F[B-]1(OC(C(O1)=O)=O)F.[Li+]

InChI

1S/C2BF2O4.Li/c4-3(5)8-1(6)2(7)9-3;/q-1;+1

Clave InChI

MEDDCIKGDMDORY-UHFFFAOYSA-N

Descripción general

Lithium difluoro(oxalato)borate (LIODFB) is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Aplicación

Lithium difluorooxalatoborate (LIODFB) is a salt for high-performance Li-ion batteries with improved cycle life; power capability; low temperature and high rate performance of the battery. It has the advantages of both lithium bis(oxalato)borate (LiBOB) and LiBF4. LIODFB also stabilizes the solid electrolyte interface (SEI) on the surface of a graphite anode and is also used as an additive to improve the cycling efficiency and capacity retention of cells
Our battery grade lithium difluorooxalatoborate (LiODFB) is a thermally stable salt and an electrolytic additive for lithium-ion batteries. LIODFB facilitates the formation of stable solid electrolyte interphase (SEI) on the negative electrode, which enhances the cycling efficiency and safety of the battery. Moreover, LiODFB is capable of stabilizing the solid electrolyte interface (SEI) on the surface of lithium metal, graphite, and silicon anode materials, substantially enhances the cyclic performance, capacity and power retention of the electrochemical cells.[5][6][7] In particular, LiODFB is suitable for high-performance Li-ion batteries operating at low temperatures and fast charge and discharge rates.

Características y beneficios

LiODFB improves the efficiency and safety of lithium-ion batteries, allowing them to deliver better performance over a longer time.
✔ Increases battery life
✔ Stabilizes SEI layer
✔ Suitable for fast charging and low temperatures

Pictogramas

Exclamation mark

Palabra de señalización

Warning

Frases de peligro

Clasificaciones de peligro

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Órganos de actuación

Respiratory system

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable


Certificados de análisis (COA)

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Visite la Librería de documentos

S. Dalavi;
Journal of the Electrochemical Society, 159(5), A642-A642 (2012)
S. S. Zhang;
Electrochemical Communications, 8(9), 1423-1428 (2006)
Lithium difluoro (oxalato) borate as a functional additive for lithium-ion batteries
Liu, Jun and Chen, Zonghai and Busking, Sara and Amine, K
Electrochemical Communications, 9(3), 475-479 (2007)
Lithium difluoro (oxalato) borate as additive to improve the thermal stability of lithiated graphite
Chen, Zonghai and Qin, Yan and Liu, Jun and Amine, K
Electrochemical and Solid-State Letters, 12(4), A69-A69 (2009)
A novel gel electrolyte with lithium difluoro (oxalato) borate salt and Sb2O3 nanoparticles for lithium ion batteries
Aravindan, V and Vickraman, P
Solid State Sciences, 9(11), 1069-1073 (2007)

Artículos

Solid-state Li batteries: Review of solid electrolytes, ion conduction, structures, and electrochemical processes.

Lithium-ion batteries offer high energy density and cyclic performance for portable electronic devices.

Li-ion batteries are currently the focus of numerous research efforts with applications designed to reduce carbon-based emissions and improve energy storage capabilities.

The critical technical challenges associated with the commercialization of electric vehicle batteries include cost, performance, abuse tolerance, and lifespan.

Ver todo

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