358711

Tetraethylammoniumcyanid

94%

• Synonym(e): N,N,N-triethyl-ethanaminium cyanide
• Lineare Formel: (C₂H₅)₄N(CN)
• CAS-Nummer: 13435-20-6
• Molekulargewicht: 156.27
• Beilstein: 3570222
• EG-Nummer: 236-566-2
• MDL-Nummer: MFCD00066552
• UNSPSC-Code: 12352116
• PubChem Substanz-ID: 24861985
• NACRES: NA.22

Eigenschaften

• Assay: 94%
• Form: powder
• mp (Schmelzpunkt): 250 °C (dec.) (lit.)
• SMILES String: [C-]#N.CC[N+](CC)(CC)CC
• InChI: 1S/C8H20N.CN/c1-5-9(6-2,7-3)8-4;1-2/h5-8H2,1-4H3;/q+1;-1
• InChIKey: PCZOZSATUTWXIC-UHFFFAOYSA-N

Beschreibung

Anwendung

Tetraethylammonium cyanide can be used:

• As a cyanide source for 1,4-addition of cyano group to enones (chalcones) catalyzed by scandium(III) triflate to yield β-cyanoketones.
• Along with diethylazodicarboxylate (DEAD) in the regioselective C- or N- ethoxy-carbonylation of heterocyclic systems like indoles and indazoles.
• In the synthesis of C-C-bridged bis-isoflavones from 2-bromomethyl-7,4′-dimethoxyisoflavone.

Tetraethylammonium cyanide is a versatile reagent commonly used in cyanation reactions as cyanide source. It is also used in the preparation of various cyanometalate complexes.

Sicherheitshinweise

• Piktogramme: GHS06,GHS09
• Signalwort: Danger
• H-Sätze: H300 + H310 + H330,H410
• P-Sätze: P262 - P264 - P273 - P280 - P302 + P352 + P310 - P304 + P340 + P310
• Gefahreneinstufungen: Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1
• Zusätzliche Gefahrenhinweise: EUH032
• Lagerklassenschlüssel: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges