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Merck

262099

Sigma-Aldrich

Phosphor(V)-oxychlorid

99.999%

Synonym(e):

Phosphoroxidchlorid, Phosphorylchlorid

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About This Item

Lineare Formel:
POCl3
CAS-Nummer:
Molekulargewicht:
153.33
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352101
PubChem Substanz-ID:
NACRES:
NA.22
bp:
105.8 °C (lit.)
Preise und Verfügbarkeit sind derzeit nicht verfügbar.

Dampfdichte

5.3 (vs air)

Qualitätsniveau

Dampfdruck

104 mmHg ( 50 °C)
28 mmHg ( 20 °C)

Assay

99.999%

Form

liquid

pH-Wert

1 (20 °C)

bp

105.8 °C (lit.)

mp (Schmelzpunkt)

1.25 °C (lit.)

Dichte

1.645 g/mL at 25 °C (lit.)

Funktionelle Gruppe

phosphine oxide

SMILES String

ClP(Cl)(Cl)=O

InChI

1S/Cl3OP/c1-5(2,3)4

InChIKey

XHXFXVLFKHQFAL-UHFFFAOYSA-N

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Anwendung

Phosphorus(V) oxychloride can be used as:
  • A dehydrating agent in organic synthesis.[1]
  • A reagent in the cyclization of substituted aryl amides by Bischler−Napieralski cyclization reaction.[2]
  • A precursor for phosphorus diffusion in the p-type silicon solar cells processing.[3]

It can also be used in the Vilsmeier-Haack reaction to synthesize aromatic aldehydes.[4]

Zubehör

Produkt-Nr.
Beschreibung
Preisangaben

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 1 Inhalation

Zielorgane

Respiratory Tract

Zusätzliche Gefahrenhinweise

Lagerklassenschlüssel

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Analysenzertifikate (COA)

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Optimization of phosphorus emitter formation from POCl 3 diffusion for p-type silicon solar cells processing
Ghembaza H, et al.
Silicon, 10(2), 377-386 (2018)
Rapid one-pot radiosynthesis of [carbonyl-. sup. 11C] formamides from primary amines and [. sup. 11C] CO. sub. 2.
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POCl(3)-mediated one-pot macrocyclization allows the highly selective formation of five-residue macrocycles that are rigidified by internally placed intramolecular hydrogen bonds. Mechanistic investigation by using tailored competition experiments and kinetic simulation provides a comprehensive model, supporting a chain-growth mechanism underlying the

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 Antwort
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 Antwort
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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