256021

(Trimethylsilyl)methylmagnesiumchlorid -Lösung

1.0 M in diethyl ether

• Synonym(e): (Trimethylsilyl)methyl magnesium chloride, Chloro(trimethylsilylmethyl)magnesium
• Lineare Formel: (CH₃)₃SiCH₂MgCl
• CAS-Nummer: 13170-43-9
• Molekulargewicht: 146.97
• Beilstein: 3587255
• MDL-Nummer: MFCD00009916
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24855503
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Eignung der Reaktion: reaction type: Grignard Reaction
• Konzentration: 1.0 M in diethyl ether
• Dichte: 0.777 g/mL at 25 °C
• SMILES String: C[Si](C)(C)C[Mg]Cl
• InChI: 1S/C4H11Si.ClH.Mg/c1-5(2,3)4;;/h1H2,2-4H3;1H;/q;;+1/p-1
• InChIKey: NAQATMJWCJCHOZ-UHFFFAOYSA-M

Beschreibung

Anwendung

Reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals, cross-coupling with aryl triflates and carbamates, and cross-coupling with vinyl selenides.

Sicherheitshinweise

• Piktogramme: GHS02,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H225,H302,H314,H336
• P-Sätze: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• Zielorgane: Central nervous system
• Zusätzliche Gefahrenhinweise: EUH014,EUH019
• Lagerklassenschlüssel: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flammpunkt (°F): -40.0 °F - closed cup
• Flammpunkt (°C): -40 °C - closed cup
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter