918997

AndrewPhos

≥95%

• Synonyma: 14,14-Dimethyl-13-(3-methoxy-2′,4′,6′-triisopropyl-[1,1′-biphenyl]-2-yl)-1,4-dioxa-13-phosphadispiro[4.1.5.3]pentadecane
• Empirický vzorec (Hillův zápis): C₃₆H₅₃O₃P
• Číslo CAS: 2380310-03-0
• Molekulová hmotnost: 564.78
• MDL number: MFCD34549923
• UNSPSC Code: 12352112
• NACRES: NA.22

Vlastnosti

• Quality Level: 100
• assay: ≥95%
• form: powder
• reaction suitability: reagent type: catalyst; reaction type: Cross Couplings; reagent type: ligand
• functional group: phosphine
• Storage temp.: −20°C
• SMILES string: P3(C4(CC5(OCCO5)CC3(C)C)CCCCC4)c1c(cccc1c2c(cc(cc2C(C)C)C(C)C)C(C)C)OC
• Inchi Key: CNDZLFAQJZQSQK-UHFFFAOYSA-N

Popis

Application

AndrewPhos is a biaryl phosphorinane ligand for Pd catalysis. This ligand has been used in a variety of Pd-catalyzed reactions including the sulfonamidation of aryl halides, C-O couplings, and C-N couplings.

Other Notes

Pd-Catalyzed Cross-Coupling Reactions Promoted by Biaryl Phosphorinane Ligands

Bezpečnostní informace

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable