499307

Phenethylzinc bromide solution

0.5 M in THF

• Lineární vzorec: C₆H₅CH₂CH₂ZnBr
• Číslo CAS: 308796-14-7
• Molekulová hmotnost: 250.45
• MDL number: MFCD01311437
• UNSPSC Code: 12352103
• PubChem Substance ID: 24873270
• NACRES: NA.22

Vlastnosti

• Quality Level: 100
• concentration: 0.5 M in THF
• bp: 65 °C
• density: 0.965 g/mL at 25 °C
• functional group: phenyl
• storage temp.: 2-8°C
• SMILES string: Br[Zn]CCc1ccccc1
• InChI: 1S/C8H9.BrH.Zn/c1-2-8-6-4-3-5-7-8;;/h3-7H,1-2H2;1H;/q;;+1/p-1
• InChI key: SEXSOTWHLBYVNF-UHFFFAOYSA-M

Popis

Application

Phenethylzinc bromide can be used as a reagent:

• In the transition metal-catalyzed Negishi cross-coupling reaction to prepare aryl or heteroaryl derivatives by reacting with organic halides or triflates via carbon-carbon bond formation.
• To prepare (4-phenyl-1-butyn-1-yl)benzene by reacting with phenylacetylene via palladium-catalyzed cross-coupling reaction.
• To synthesize benzyl substituted thienopyrimidine derivatives.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Bezpečnostní informace

• pictograms: GHS02,GHS08,GHS07
• signalword: Danger
• hcodes: H225,H319,H335,H336,H351
• pcodes: P202 - P210 - P233 - P240 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• target_organs: Central nervous system, Respiratory system
• supp_hazards: EUH014,EUH019
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 1.4 °F - closed cup
• flash_point_c: -17 °C - closed cup