395099

Tris(4-fluorophenyl)phosphine

98%

• Synonyma: Tri-(p-fluorophenyl)phosphine
• Lineární vzorec: (FC₆H₄)₃P
• Číslo CAS: 18437-78-0
• Molekulová hmotnost: 316.26
• Beilstein/REAXYS Number: 919838
• MDL number: MFCD00013553
• UNSPSC Code: 12352101
• PubChem Substance ID: 24864642
• NACRES: NA.22

Vlastnosti

• assay: 98%
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 79-83 °C (lit.)
• functional group: phosphine
• greener alternative category: Aligned,
• SMILES string: Fc1ccc(cc1)P(c2ccc(F)cc2)c3ccc(F)cc3
• InChI: 1S/C18H12F3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H
• InChI key: GEPJPYNDFSOARB-UHFFFAOYSA-N

Popis

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Ligand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids

Bezpečnostní informace

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves