327611

Pentacarbonylchlororhenium(I)

98%

• Synonyma: Rhenium(I) pentacarbonyl chloride
• Lineární vzorec: Re(CO)₅Cl
• Číslo CAS: 14099-01-5
• Molekulová hmotnost: 361.71
• EC Number: 237-948-1
• MDL number: MFCD00013296
• UNSPSC Code: 12161600
• PubChem Substance ID: 24859674
• NACRES: NA.22

Vlastnosti

• Quality Level: 100
• assay: 98%
• reaction suitability: core: rhenium; reagent type: catalyst
• SMILES string: Cl[Re].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
• InChI: 1S/5CO.ClH.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
• InChI key: JQUUAHKBIXPQAP-UHFFFAOYSA-M

Popis

Application

Used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands and also to prepare [3]-ferrocenophane complexes. Employed in preparation of a series of mixed-valence compounds of rhenium and iron these compounds find application in the study of charge-transfer processes.

Other Notes

For a review of organometallic complexes of rhenium, see Science of Synthesis.

Bezpečnostní informace

• pictograms: GHS06
• signalword: Danger
• hcodes: H301 + H311 + H331,H315,H319,H335
• pcodes: P261 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk_germany: WGK 3
• ppe: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges