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COO/COA

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292966

1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate

Name: 1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate
Brand: ALDRICH

95%

Synonyma:

BNDHP

Přihlásitk zobrazení cen stanovených pro organizaci a smluvních cen

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About This Item

Empirický vzorec (Hillův zápis):

C₂₀H₁₃O₄P

Číslo CAS:

35193-63-6

Molekulová hmotnost:

348.29

EC Number:

252-425-8

MDL number:

MFCD00010045

UNSPSC Code:

12352005

PubChem Substance ID:

24857622

NACRES:

NA.22

Doporučené produkty

Slide 1 of 10

1 of 10

Sigma-Aldrich

248932

(R)-(−)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate

Sigma-Aldrich

850608

Diphenyl phosphate

Sigma-Aldrich

248940

(S)-(+)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate

Sigma-Aldrich

43153

Diphenylphosphinic acid

Sigma-Aldrich

237744

(S)-(+)-1,2-Isopropylideneglycerol

Sigma-Aldrich

122696

DL-1,2-Isopropylideneglycerol

Sigma-Aldrich

D27802

1,4-Diazabicyclo[2.2.2]octane

Sigma-Aldrich

454486

(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde

Sigma-Aldrich

345571

1,5,7-Triazabicyclo[4.4.0]dec-5-ene

Sigma-Aldrich

139009

1,8-Diazabicyclo[5.4.0]undec-7-ene

assay

95%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling

SMILES string

OP1(=O)Oc2ccc3ccccc3c2-c4c(O1)ccc5ccccc45

InChI

1S/C20H13O4P/c21-25(22)23-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)24-25/h1-12H,(H,21,22)

Inchi Key

JEHUZVBIUCAMRZ-UHFFFAOYSA-N

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Osvědčení o analýze (COA)

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Slide 1 of 6

1 of 6

Sigma-Aldrich

700665

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

Sigma-Aldrich

717738

(S)-3,3′-Bis(9-anthracenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

Sigma-Aldrich

689785

(S)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

Sigma-Aldrich

908568

[Ir(dFCF₃ppy)₂-(5,5′-dCF₃bpy)]PF₆

Sigma-Aldrich

D36550

Dibenzyl phosphate

Sigma-Aldrich

663042

CX22

Sodium cholate aggregation and chiral recognition of the probe molecule (R,S)-1,1'-binaphthyl-2,2'-diylhydrogenphosphate (BNDHP) observed by 1H and 31P NMR spectroscopy.

Christine M Hebling et al.

Langmuir : the ACS journal of surfaces and colloids, 24(24), 13866-13874 (2008-12-05)

Bile salt micelles can be employed as a pseudostationary phase in micellar electrokinetic capillary chromatography (MEKC) separations of chiral analytes. To improve MEKC separations of chiral analytes, a molecular level understanding of micelle aggregation in the presence of analyte is

Fluorescence anisotropy as a measure of chiral recognition.

M E McCarroll et al.

Journal of the American Chemical Society, 123(13), 3173-3174 (2001-07-18)

Chiral selectivity of guanosine media in capillary electrophoresis.

Yingying Dong et al.

Electrophoresis, 32(13), 1735-1741 (2011-06-28)

Gels formed by self-association of monomeric guanosine compounds join numerous other agents such as cyclodextrins, crown ethers, chiral surfactants, antibiotics, proteins, and polysaccharides for chiral separations. Guanosine gels (G-gels) are self-assembled networks of hydrogen-bonded tetrads formed by guanosine nucleotides and

Comparative study on the enantiomer separation of 1,1'-binaphthyl-2,2'diyl hydrogenphosphate and 1,1'-bi-2-naphthol by liquid chromatography and capillary electrophoresis using single and combined chiral selector systems.

Anna Bielejewska et al.

Journal of chromatography. A, 977(2), 225-237 (2002-11-29)

The chiral recognition ability of single and dual selectors, that were used as additives, have been investigated by HPLC and CE. Native beta- and gamma-cyclodextrins, permethylated beta-cyclodextrin, hydroxypropyl-beta-cyclodextrin, cholic acid and taurodeoxycholic acid sodium salts were applied as chiral selectors

Enantioseparation using selected polysaccharides as chiral buffer additives in capillary electrophoresis.

B Chankvetadze et al.

Journal of chromatography. A, 773(1-2), 331-338 (1997-06-27)

Selected water-soluble, native polysaccharides--such as amylose, laminaran, pullulan--and derivatized polysaccharides--methyl cellulose, hydroxypropyl cellulose, and carboxymethyl amylose sodium salt (CM-Am)--were investigated as chiral selectors in capillary electrophoresis. Effects of degree of polymerization and concentration of amylose on the separation of enantiomers

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Key Documents

1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate

95%

About This Item

Doporučené produkty

Vlastnosti

assay

form

reaction suitability

SMILES string

InChI

Inchi Key

Bezpečnostní informace

Storage Class

wgk_germany

flash_point_f

flash_point_c

ppe

Dokumentace

Osvědčení o analýze (COA)

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Zákazníci si také prohlíželi

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