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Key Documents

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75707

Sigma-Aldrich

Bis(2,4,6-trichlorophenyl) oxalate

BioReagent, suitable for chemiluminescence, ≥99.0% (AT)

Sinónimos:

2,4,6-Trichlorophenyl oxalate, Oxalic acid bis(2,4,6-trichlorophenyl) ester, TCPO

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About This Item

Fórmula empírica (notación de Hill):
C14H4Cl6O4
Número de CAS:
1165-91-9
Peso molecular:
448.90
Beilstein/REAXYS Number:
2312135
MDL number:
MFCD00043061
UNSPSC Code:
12352209
PubChem Substance ID:
329766641
NACRES:
NA.32

product line

BioReagent

Quality Level

100

assay

≥99.0% (AT)

form

crystals

mp

187-193 °C

suitability

suitable for chemiluminescence

SMILES string

Clc1cc(Cl)c(OC(=O)C(=O)Oc2c(Cl)cc(Cl)cc2Cl)c(Cl)c1

InChI

1S/C14H4Cl6O4/c15-5-1-7(17)11(8(18)2-5)23-13(21)14(22)24-12-9(19)3-6(16)4-10(12)20/h1-4H

InChI key

GEVPIWPYWJZSPR-UHFFFAOYSA-N

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Analysis Note

Chemiluminescence: Emission: 430 nm (reaction of TCPO with 9,10-Diphenylanthracene and H2O2)

Other Notes

Widely used reagent for the generation of chemiluminescence with H2O2. Used for the determination of fluorescent compounds; Used in the determination of H2O2 with a fluorophore

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Ruy C M C Ferraz et al.
Journal of photochemistry and photobiology. B, Biology, 103(2), 87-92 (2011-02-26)
The photodynamic therapy (PDT) is a combination of using a photosensitizer agent, light and oxygen that can cause oxidative cellular damage. This technique is applied in several cases, including for microbial control. The most extensively studied light sources for this
Evaluation of peroxyoxalate chemiluminescence for determination of enzyme generated peroxide.
D C Williams et al.
Analytical chemistry, 48(7), 1003-1006 (1976-06-01)
Mojtaba Shamsipur et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 59(3), 511-517 (2003-01-14)
The chemiluminescence arising from the reaction of bis(2,4,6-trichlorophenyl)oxalate (TCPO) with hydrogen peroxide in the presence of acriflavine has been studied. The relationship between the chemiluminescence intensity and concentrations of TCPO, H2O2, acriflavine and the base sodium salicylate are reported. The
Aikaterini Koutsaviti et al.
Foods (Basel, Switzerland), 10(1) (2021-01-16)
The antioxidant activity of the essential oils, as well as of the organic and hydroethanolic extracts, of the fresh needles of 54 pine taxa was evaluated using the peroxy-oxalate and luminol chemiluminescence assays. Among all evaluated essential oils, P. canariensis
T.G. Curtis et al.
Journal of Chromatography A, 134, 434-434 (1977)
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