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B56501

Sigma-Aldrich

4-Bromoanisole

≥99.0%

Sinónimos:

1-Bromo-4-methoxybenzene

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About This Item

Fórmula lineal:
BrC6H4OCH3
Número de CAS:
104-92-7
Peso molecular:
187.03
Beilstein/REAXYS Number:
1237590
EC Number:
203-252-1
MDL number:
MFCD00000097
UNSPSC Code:
12352100
PubChem Substance ID:
24891850
NACRES:
NA.22

Quality Level

100

assay

≥99.0%

form

liquid

refractive index

n20/D 1.564 (lit.)

bp

223 °C (lit.)

mp

9-10 °C (lit.)

density

1.494 g/mL at 25 °C (lit.)

SMILES string

COc1ccc(Br)cc1

InChI

1S/C7H7BrO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3

InChI key

QJPJQTDYNZXKQF-UHFFFAOYSA-N

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General description

4-Bromoanisole is a useful brominating reagent. It is formed as reaction product in the reaction between HOBr and anisole. Suzuki coupling of 4-bromoanisole with phenylboronic acid catalyzed by palladium pincer complexes has been studied. Heck Reaction of 4-bromoanisole with ethyl acrylates in room-temperature ionic liquids is reported to afford ethyl 4-methoxycinnamate.

Application

4-Bromoanisole was used in the synthesis of aryl 1,3-diketones.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H302,H315

Hazard Classifications

Acute Tox. 4 Oral - Skin Irrit. 2

Storage Class

10 - Combustible liquids

wgk_germany

WGK 2

flash_point_f

201.2 °F

flash_point_c

94 °C

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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Certificados de análisis (COA)

Lot/Batch Number
STBL3101
STBK2893
STBJ3720
STBH8191
STBH4159

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Anisole analytical standard

Supelco

96109

Anisole

4′-Bromoacetophenone 98%

Sigma-Aldrich

B56404

4′-Bromoacetophenone

4-Methoxyphenylboronic acid ≥95.0%

Sigma-Aldrich

417599

4-Methoxyphenylboronic acid

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