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Merck
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550256

Sigma-Aldrich

Silver methanesulfonate

Sinónimos:

Silver methylsulfonate, Methanesulfonic acid silver salt

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About This Item

Fórmula lineal:
AgSO3CH3
Número de CAS:
2386-52-9
Peso molecular:
202.97
Número CE:
219-199-2
Número MDL:
MFCD00064795
Código UNSPSC:
12161600
ID de la sustancia en PubChem:
24879101
NACRES:
NA.22

Formulario

solid

Nivel de calidad

100

idoneidad de la reacción

core: silver
reagent type: catalyst

mp

252-256 °C (lit.)

cadena SMILES

[Ag+].CS([O-])(=O)=O

InChI

1S/CH4O3S.Ag/c1-5(2,3)4;/h1H3,(H,2,3,4);/q;+1/p-1

Clave InChI

MLKQJVFHEUORBO-UHFFFAOYSA-M

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Categorías relacionadas

Aplicación

Gold Catalysts — 21st Century ′Gold Rush′
Catalyst for:
  • Heterocyclization reactions
  • CO2-mediated rearrangement of propargyl alcohols for the synthesis of a,ß-unsaturated ketones and esters

Pictogramas

Exclamation mark
GHS07

Palabra de señalización

Warning

Frases de peligro

H315,H319,H335

Clasificaciones de peligro

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Órganos de actuación

Respiratory system

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

dust mask type N95 (US), Eyeshields, Gloves

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Certificados de análisis (COA)

Lot/Batch Number
MKCS7124
MKCR3717
MKCR8945
MKCQ5160
MKCM2372

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Eric D Nacsa et al.
Organic letters, 15(1), 38-41 (2012-12-15)
The cyclopropenone catalyzed nucleophilic substitution of alcohols by methanesulfonate ion with inversion of configuration is described. This work provides an alternative to the Mitsunobu reaction that avoids the use of azodicarboxylates and generation of hydrazine and phosphine oxide byproducts. This
Claudio Pettinari et al.
Inorganic chemistry, 50(21), 11173-11183 (2011-10-18)
Five new silver(I) complexes of formulas [Ag(Tpms)] (1), [Ag(Tpms)(PPh(3))] (2), [Ag(Tpms)(PCy(3))] (3), [Ag(PTA)][BF(4)] (4), and [Ag(Tpms)(PTA)] (5) {Tpms = tris(pyrazol-1-yl)methanesulfonate, PPh(3) = triphenylphosphane, PCy(3) = tricyclohexylphosphane, PTA = 1,3,5-triaza-7-phosphaadamantane} have been synthesized and fully characterized by elemental analyses, (1)H, (13)C
Chad E Wujcik et al.
Journal of separation science, 33(6-7), 826-833 (2010-01-21)
Hydrophilic retention coefficients for 17 peptides were calculated based on retention coefficients previously published for TSKgel silica-60 and were compared with the experimental elution profile on a Waters Atlantis HILIC silica column using TFA and methanesulfonic acid (MSA) as ion-pairing
Siddheshwar K Chauthe et al.
Bioorganic & medicinal chemistry letters, 22(6), 2251-2256 (2012-02-22)
A series of dimeric phloroglucinol compounds were synthesized in a single step using commercially available phloroglucinol and methanesulfonic acid. Based on the reported anticancer activity of plant derived dimeric phloroglucinols, these synthesized compounds were evaluated for their in vitro anti-proliferative
Benedetto Natalini et al.
Talanta, 85(3), 1392-1397 (2011-08-03)
The successful enantioseparation of five 6-desfluoroquinolones with three polysaccharide-based stationary phases (namely, the cellulose-based Chiralpak IB and the two amylose-based Chiralpak AD-H and Lux Amylose-2) is herein described. The investigated species differ for the nature of substituents and/or the position
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