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Merck

369500

Sigma-Aldrich

4,4′-Methylenebis(2-methylcyclohexylamine), mixture of isomers

99%

Sinónimos:

2,2′-Dimethyl-4,4′-methylenebis(cyclohexylamine), 3,3′-Dimethyl-4,4′-diaminodicyclohexylmethane, 4,4′-Diamino-3,3′-dimethyldicyclohexylmethane, Bis(3-methyl-4-aminocyclohexyl)methane, DMDC, Dimethyldicykan

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About This Item

Fórmula lineal:
CH2[C6H9(CH3)NH2]2
Número de CAS:
Peso molecular:
238.41
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

99%

form

liquid

refractive index

n20/D 1.499 (lit.)

bp

93-100 °C (lit.)

density

0.94 g/mL at 25 °C (lit.)

SMILES string

CC1CC(CCC1N)CC2CCC(N)C(C)C2

InChI

1S/C15H30N2/c1-10-7-12(3-5-14(10)16)9-13-4-6-15(17)11(2)8-13/h10-15H,3-9,16-17H2,1-2H3

InChI key

IGSBHTZEJMPDSZ-UHFFFAOYSA-N

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General description

4,4′-Methylenebis(2-methylcyclohexylamine) is an alicyclic diamine.

Application

4,4′-Methylenebis(2-methylcyclohexylamine) (MMCA) may be used:
  • in the synthesis of fully aliphatic polyimides
  • in the synthesis of fully aliphatic polyimide-siloxanes (APISiO)
  • to prepare epoxy resin with trimethylolpropane triglycidyl ether, used for the characterization of the structural organization in dragline silk by transmission X-ray microscopy (STXM).

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Corr. 1A

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

343.4 °F - closed cup

flash_point_c

173 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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H Ishikawa et al.
Dermatologica, 161(3), 145-151 (1980-01-01)
The presence of sclerosis-inducing glycosaminoglycan in the skin was confirmed in an experimental skin sclerosis induced by a chemical compound. An experimental skin sclerosis was first produced in the mouse with bis(4-amino-3-methylcyclohexyl)methane. Out of glycosaminoglycans isolated from the slightly changed
S Ohshima et al.
Sangyo igaku. Japanese journal of industrial health, 26(3), 197-204 (1984-05-01)
Amine-curing agent for epoxy resin, bis(4-amino-3-methylcyclohexyl)methane, has been suspected of inducing toxic symptoms in man which resemble collagen disease such as scleroderma or polymyositis. We studied subacute toxicity of this agent by repeated oral administrations to rats. The agent was
T Shibata et al.
Virchows Archiv. A, Pathological anatomy and histopathology, 417(3), 203-212 (1990-01-01)
Repeated oral administration of an amine-curing agent for epoxy resin, bis(4-amino-3-methylcyclohexyl)methane, gave rise to severe damage in the choroid plexus of rat brain. The damaged epithelium presented varying degrees of swelling and hydropic vacuolation on light microscopy, and varying numbers
S Ohshima et al.
The Journal of toxicological sciences, 11(2), 79-93 (1986-05-01)
Amine-curing agent for epoxy resin, bis(4-amino-3-methyl-cyclohexyl)methane (commercial name; Laromin C) has been suspected to have induced in the workers some toxic signs such as collagen disease like scleroderma or polymyositis. Subacute toxicity of this agent was studied in rats following
Fully aliphatic polyimides from adamantane-based diamines for enhanced thermal stability, solubility, transparency, and low dielectric constant.
Mathews AS, et al.
Journal of Applied Polymer Science, 102(4), 3316-3326 (2006)

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