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309206

Sigma-Aldrich

Rhodium(III) nitrate solution

~10 % (w/w) (Rh in >5 wt. % HNO3)

Sinónimos:

Aqueous rhodium nitrate, Rhodium trinitrate, Rhodium(3+)trinitrate

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About This Item

Fórmula lineal:
Rh(NO3)3
Peso molecular:
288.92
MDL number:
MFCD00011201
UNSPSC Code:
12352302
PubChem Substance ID:
24858717
NACRES:
NA.23

form

liquid

Quality Level

100

concentration

≥5.0% (NaOH basis (wt% HNO3, titration))
~10 % (w/w) (Rh in >5 wt. % HNO3)

density

1.41 g/mL at 25 °C

SMILES string

[Rh]

InChI

1S/Rh

Inchi Key

MHOVAHRLVXNVSD-UHFFFAOYSA-N

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Application

  • The saga of rhodium (III) nitrate complexes and their speciation in solution: An integrated experimental and quantum chemical study of rhodium(III) nitrate complexes in solution (SN Vorobyeva et al., 2022).

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Eye Dam. 1 - Met. Corr. 1 - Ox. Liq. 3 - Skin Corr. 1A

supp_hazards

EUH071

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number
MKCW4989
MKCV9665
MKCV1210
MKCT5687
MKCR9518

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Dong Jin Lee et al.
Angewandte Chemie (International ed. in English), 54(46), 13715-13718 (2015-09-18)
A new type of intermolecular rhodium(II)-catalyzed [5+3] cycloaddition has been developed. This higher-order cycloaddition between pyridinium zwitterion 1,5-dipole equivalents and enol diazoacetates enables the formation of eight-membered heterocyclic skeletons, which are otherwise difficult to construct. The optimized cycloaddition occurs efficiently under
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Journal of hazardous materials, 298, 282-293 (2015-06-16)
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A regio-, diastereo-, and enantioselective [4+3] cycloaddition between vinylcarbenes and dienes has been achieved using the dirhodium tetracarboxylate catalyst [Rh2(S-BTPCP)4]. This methodology provides facile access to 1,4-cycloheptadienes that are regioisomers of those formed from the tandem cyclopropanation/Cope rearrangement reaction of
Chumin Zhao et al.
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Nutrients, 7(1), 608-624 (2015-01-20)
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