695459

1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamante

97%

• Sinónimos: 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane, ^meCgPPh
• Fórmula empírica (notación de Hill): C₁₆H₂₁O₃P
• Número de CAS: 97739-46-3
• Peso molecular: 292.31
• Número MDL: MFCD30541356
• Código UNSPSC: 12352005
• ID de la sustancia en PubChem: 329761744
• NACRES: NA.22

Propiedades

• Ensayo: 97%
• Formulario: solid
• idoneidad de la reacción: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Cross Couplings
• mp: 106-111 °C
• grupo funcional: phosphine
• cadena SMILES: CC12CC3(C)OC(C)(CC(C)(O1)P3c4ccccc4)O2
• InChI: 1S/C16H21O3P/c1-13-10-15(3)19-14(2,17-13)11-16(4,18-13)20(15)12-8-6-5-7-9-12/h5-9H,10-11H2,1-4H3
• Clave InChI: AVVSJWUWBATQBX-UHFFFAOYSA-N

Descripción

Aplicación

1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane can be used:

• As a ligand to synthesize complexes for hydroformylation catalysis.
• To catalyze the synthesis of dibenzo[b,f][1,4]oxazepin-11(10H)-ones and 3-methyl-3,4-dihydrocoumarins by intramolecular cyclocarbonylation.

Información de seguridad

• Código de clase de almacenamiento: 11 - Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable