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412910

Sigma-Aldrich

Methyltrioxorhenium(VII)

Re 71.0-76.0 %

Sinónimos:

MTO, Methylrhenium(VII) trioxide

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About This Item

Fórmula lineal:
CH3ReO3
Número de CAS:
70197-13-6
Peso molecular:
249.24
Beilstein/REAXYS Number:
3927932
MDL number:
MFCD00192332
UNSPSC Code:
12161600
PubChem Substance ID:
24865831
NACRES:
NA.22

form

solid

composition

Re, 71.0-76.0%

reaction suitability

core: rhenium
reagent type: catalyst

mp

111 °C (lit.)

SMILES string

C[Re](=O)(=O)=O

InChI

1S/CH3.3O.Re/h1H3;;;;

InChI key

PQTLALPZRPFYIT-UHFFFAOYSA-N

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Application

Potent catalytic oxidant for converting alkenes to epoxides in a variety of solvents and 2-methylnaphthalene to 2-methyl-1,4-naphthoquinone (Vitamin K3).
Catalytic oxidant used with urea hydrogen peroxide in an efficient conversion of imines to nitrones.
An effective antioxidant under various conditions.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Steven W Baldwin et al.
Organic letters, 6(10), 1653-1656 (2004-05-07)
Cycloaddition reactions between a new homochiral imidazolone-derived nitrone afford cycloadducts in high yield and with high stereoselectivity. Subsequent cycloadduct elaboration affords the gamma-lactones of gamma-hydroxy-alpha-amino acids as well as the optically pure amino acids themselves.
Bee Hong Soon et al.
Frontiers in physiology, 8, 231-231 (2017-05-10)
The role of mitochondria in tumorigenesis has regained much attention as it could dysregulate cellular energetics, oxidative stress and apoptosis. However, the role of mitochondria in different grade gliomasis still unknown. This study aimed to identify mitochondrial DNA (mtDNA) sequence
Veronika Huntosova et al.
Molecules (Basel, Switzerland), 26(2) (2021-01-23)
Detection of tissue and cell oxygenation is of high importance in fundamental biological and in many medical applications, particularly for monitoring dysfunction in the early stages of cancer. Measurements of the luminescence lifetimes of molecular probes offer a very promising
Shaunak Sen et al.
ACS synthetic biology, 6(8), 1461-1470 (2017-04-25)
Biomolecular temperature sensors can be used for efficient control of large-volume bioreactors, for spatiotemporal imaging and control of gene expression, and to engineer robustness to temperature in biomolecular circuit design. Although RNA-based sensors, called "thermometers", have been investigated in both
Journal of the American Chemical Society, 116, 2869-2869 (1994)
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