393290

Tris(dimethylamino)phosphine

97%

• Sinónimos: (Me₂N)₃P, Hexamethyltriamidophosphite, Hexamethyltriaminophosphine, HMPT, Hexamethylphosphorous triamide
• Fórmula lineal: P[N(CH₃)₂]₃
• Número de CAS: 1608-26-0
• Peso molecular: 163.20
• Beilstein/REAXYS Number: 906778
• MDL number: MFCD00008301
• UNSPSC Code: 12161700
• PubChem Substance ID: 24864511
• NACRES: NA.22

Propiedades

• Quality Level: 100
• assay: 97%
• form: liquid
• reaction suitability: reagent type: ligand; reaction type: Reductions; reagent type: ligand; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Wittig Reaction
• refractive index: n20/D 1.463 (lit.)
• bp: 48-50 °C/12 mmHg (lit.)
• density: 0.898 g/mL at 25 °C (lit.)
• functional group: phosphine
• SMILES string: CN(C)P(N(C)C)N(C)C
• InChI: 1S/C6H18N3P/c1-7(2)10(8(3)4)9(5)6/h1-6H3
• InChI key: XVDBWWRIXBMVJV-UHFFFAOYSA-N

Descripción

Application

Tris(dimethylamino)phosphine can be used a reagent in combination with CCl4 for the conversion of hydroxyl groups to the corresponding chlorides; for hydroxyl group activation; dehydrations.

Tris(dimethylamino)phosphine can be used as a:

• Ligand in the preparation of arene-ruthenium(II) complex which is used as a catalyst in hydration of nitriles to amides.
• Phosphorus source along with InCl₃ in the synthesis of InP colloidal quantum dots (QDs).
• Deoxygenating agent for some α-dicarbonyl compounds in the presence of fullerene C₆₀.

Información de seguridad

• pictograms: GHS02,GHS08,GHS07
• signalword: Danger
• hcodes: H226,H315,H319,H340,H350
• pcodes: P202 - P210 - P233 - P303 + P361 + P353 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Carc. 1B - Eye Irrit. 2 - Flam. Liq. 3 - Muta. 1B - Skin Irrit. 2
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 80.6 °F - closed cup
• flash_point_c: 27 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter