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163015

Sigma-Aldrich

Thallium(III) nitrate trihydrate

Sinónimos:

TTN, Thallium trinitrate

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About This Item

Fórmula lineal:
Tl(NO3)3 · 3H2O
Número de CAS:
13453-38-8
Peso molecular:
444.44
EC Number:
237-325-4
MDL number:
MFCD00149874
UNSPSC Code:
12161600
PubChem Substance ID:
24850018
NACRES:
NA.22

reaction suitability

core: thallium
reagent type: catalyst

mp

102-105 °C (lit.)

SMILES string

O.O.O.[Tl+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/3NO3.3H2O.Tl/c3*2-1(3)4;;;;/h;;;3*1H2;/q3*-1;;;;+3

InChI key

ZCPIKMRXMBJLCP-UHFFFAOYSA-N

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Application

Reagent for the rapid oxidation of styrene derivatives to carbonyl compounds, for the regioselective ring expansion of cyclic aralkyl ketones via oxidative rearrangement, for the selective hydrolysis of thioacetals to carbonyl compounds and for a general synthetic method to 19-norsteroids. Mediates ring contraction of cyclic ketones to a series of trans-fused 10-methyl-2-decalones.

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2

Storage Class

5.1B - Oxidizing hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Synthetic Communications, 9, 301-301 (1979)
Kevin Yauy et al.
The Journal of molecular diagnostics : JMD, 20(4), 465-473 (2018-04-25)
Interpretation of next-generation sequencing constitutes the main limitation of molecular diagnostics. In diagnosing myopathies and muscular dystrophies, another issue is efficiency in predicting the pathogenicity of variants identified in large genes, especially TTN; current in silico prediction tools show limitations
Enrico Bugiardini et al.
Frontiers in neurology, 9, 456-456 (2018-07-13)
Objective: Distal myopathies are a diagnostically challenging group of diseases. We wanted to understand the value of MRI in the current clinical setting and explore the potential for optimizing its clinical application. Methods: We retrospectively audited the diagnostic workup in
Sophie Lalande et al.
Experimental physiology, 102(9), 1055-1066 (2017-08-02)
What is the topic of this review? This review focuses on how in vivo and molecular measurements of cardiac passive stiffness can predict exercise tolerance and how exercise training can reduce cardiac passive stiffness. What advances does it highlight? This
Journal of the Chemical Society. Chemical Communications, 1026-1026 (1990)
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