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Merck

157759

Sigma-Aldrich

Sulfur monochloride

98%

Sinónimos:

Sulfur chloride

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About This Item

Fórmula lineal:
S2Cl2
Número de CAS:
Peso molecular:
135.04
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de la sustancia en PubChem:
NACRES:
NA.23
Ensayo:
98%
Formulario:
liquid
En este momento no podemos mostrarle ni los precios ni la disponibilidad

densidad de vapor

4.7 (vs air)

Nivel de calidad

presión de vapor

6.8 mmHg ( 20 °C)

Ensayo

98%

Formulario

liquid

temp. de autoignición

451 °F

índice de refracción

n20/D 1.658 (lit.)

bp

138 °C (lit.)

mp

−80 °C (lit.)

densidad

1.688 g/mL at 25 °C (lit.)

cadena SMILES

ClSSCl

InChI

1S/Cl2S2/c1-3-4-2

Clave InChI

PXJJSXABGXMUSU-UHFFFAOYSA-N

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Categorías relacionadas

Descripción general

Sulfur monochloride is a yellowish-red liquid widely used as a reagent and intermediate in organic synthesis. It is also employed in manufacturing pesticides, pharmaceuticals, and dyes.[1] [2]

Aplicación

Sulfur monochloride can be used:
  • To synthesize functionalized aryl and heteroaryl disulfides from functionalized zinc organometallics.[1]
  • As a reagent to prepare heterocycles with various numbers of sulfur atoms.[3]
  • As a cross-linking agent to prepare rubber aerogels with enhanced thermal stability.[4]
  • Toprepare macroporous cryogels of polyisobutylene and silica nanoparticles.[2]

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Skin Corr. 1A

Riesgos supl.

Código de clase de almacenamiento

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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A direct preparation of functionalized aryl and heteroaryl disulfides from functionalized zinc organometallics by using sulfur monochloride (S2Cl2
Tobias J Korn and Paul Knochel
Synlett, 2005, 1185-1187 (2005)
Solution cross-linked natural rubber(NR)/clay aerogel composite
Tassawuth Pojanavaraphan, et al
Macromolecules, 44, 923-931 (2011)
Andrea Steinhaus et al.
Polymers, 11(7) (2019-07-03)
Lamella-forming ABC triblock terpolymers are convenient building blocks for the synthesis of soft Janus nanoparticles (JNPs) by crosslinking the B domain that is "sandwiched" between A and C lamellae. Despite thorough synthetic variation of the B fraction to control the
Hierarchically Macroporous Cryogels of Polyisobutylene and Silica Nanoparticles
Deniz C. Tuncaboylu and Oguz Okay
Langmuir, 26, 7574-7581 (2010)
Sulfur monochloride in organic synthesis
Lidia Sergeevna Konstantinova and Oleg Alexeevich Rakitin
Russ. Chem. Rev., 83, 225-225 (2014)

Artículos

Colloidal quantum dots (CQDs) are semiconducting crystals of only a few nanometers (ca. 2–12 nm) coated with ligand/surfactant molecules to help prevent agglomeration.

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. What is the material of the cap for this product?

    1 answer
    1. This product packaging includes a red polypropylene screw cap.

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