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33092-U

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t-Butyldimethylsilylimidazole solution

TBDMSIM in DMF, pkg of 10 × 1 mL

Synonyme(s) :

1-(tert-Butyldiméthylsilyl)imidazole solution

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About This Item

Formule empirique (notation de Hill):
C9H18N2Si
Numéro CAS:
54925-64-3
Poids moléculaire :
182.34
Code UNSPSC :
12000000

Description

Silylation reagent

Conditionnement

pkg of 10 × 1 mL

Concentration

TBDMSIM in DMF

InChI

1S/C9H18N2Si/c1-9(2,3)12(4,5)11-7-6-10-8-11/h6-8H,1-5H3

Clé InChI

VUENSYJCBOSTCS-UHFFFAOYSA-N

Description générale

tert-Butyldimethylsilylimidazole solution is a derivatizing reagent. It is most effective for silylating multiwall carbon nanotubes (MWNT).

Application

It was used to convert oxysterols to tert-butyldimethylsilyl (TBDMSi) ethers for 18O enrichment during oxysterols determination in plasma and liver, using gas/liquid chromatography-mass spectrometry analysis.

Produit(s) apparenté(s)

Réf. du produit
Description
Tarif

19905

tert-Butyl(chloro)dimethylsilane, ≥95.0% (GC)

394882

N-tert-butyldiméthylsilyl-N-méthyltrifluoroacétamide, >97%

190500

tert-Butyldimethylsilyl chloride, reagent grade, 97%

375934

N-tert-butyldiméthylsilyl-N-méthyltrifluoroacétamide avec 1 % de tert-Butyldiméthylchlorosilane, ≥95%

473464

tert-Butylchlorodimethylsilane solution, 50 wt. % in toluene

384429

tert-Butyldimethylsilyl chloride solution, 1.0 M in methylene chloride

372951

tert-Butyldimethylsilyl chloride solution, 1.0 M in THF

226149

tert-Butyldimethylsilyl trifluoromethanesulfonate, reagent grade, 98%

250236

1-(tert-Butyldiméthylsilyl)imidazole, ≥95%

06735

tert-Butyldimethylsilyl chloride, for GC derivatization, LiChropur™, ≥99.0% (GC)

56563

tert-Butyldimethylsilyl trifluoromethanesulfonate, for GC derivatization, LiChropur™, ≥98.0% (T)

00942

N-tert-butyldiméthylsilyl-N-méthyltrifluoroacétamide avec 1 % de tert-Butyldiméthylchlorosilane, for GC derivatization, LiChropur™, ≥95.0% (GC)

Mention d'avertissement

Danger

Mentions de danger

H225,H314,H332,H360D,H412

Classification des risques

Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Skin Corr. 1A

Code de la classe de stockage

3 - Flammable liquids

Classe de danger pour l'eau (WGK)

WGK 2

Point d'éclair (°F)

71.6 °F - closed cup

Point d'éclair (°C)

22 °C - closed cup

Équipement de protection individuelle

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificats d'analyse (COA)

Lot/Batch Number
LC23687V
LC15018V
LC11365V
LC09547V
LC06662V

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Consulter la Bibliothèque de documents

O Breuer et al.
The Journal of biological chemistry, 270(35), 20278-20284 (1995-09-01)
Cholesterol oxidation products (oxysterols) have been detected in many different tissues, often at concentrations 10(3) to 10(4) times lower than cholesterol. This constitutes a considerable risk of quantitation errors, since even a minor oxidation of cholesterol during sample processing would
E.J.Corey and A. Venkateswarlu
Journal of the American Chemical Society, 94, 6190-6190 (1972)
Yury Gogotsi
Nanotubes and Nanofibers, 46-46 (2006)
D C Landrum et al.
Journal of chromatography, 483, 21-32 (1989-12-08)
The use of gas-liquid chromatography and mass spectrometry with derivatizing agents that give stable derivatives and consistent fragmentation patterns allows for accurate identification of a variety of compounds. In this study either N-methyl-N-tert.-butyldimethylsilyltrifluoroacetamide or N-tert.-butyldimethylsilylimidazole were employed to derivatize a
P Bydal et al.
Steroids, 61(6), 349-353 (1996-06-01)
Five dehydrated compounds obtained from a tert-butyldimethylsilylchloride/imidazole or an aqueous hydrochloric acid treatment of 17 alpha-butyl-3-O-methyl estradiol in refluxing solvent were purified and characterized. Three compounds were obtained from a direct vicinal proton elimination, the two others from a vicinal

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