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Merck

S5012

Sigma-Aldrich

Sodium hypophosphite monohydrate

≥99%

Sinónimos:

Sodium hypophosphite 1-hydrate, Sodiumphosphinite

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100 G
$77.000
500 G
$82.100

$77.000


Fecha estimada de envío12 de mayo de 2025


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100 G
$77.000
500 G
$82.100

About This Item

Fórmula lineal:
NaH2PO2 · H2O
Número de CAS:
Peso molecular:
105.99
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de la sustancia en PubChem:
NACRES:
NA.22

$77.000


Fecha estimada de envío12 de mayo de 2025


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Nivel de calidad

Ensayo

≥99%

Formulario

powder, crystals or chunks

pH

(6,0 - 8,0 at 50 g/l at 25 °C (77 °F))

solubilidad

water: 100 mg/mL, clear, colorless

cadena SMILES

O.[Na+].[O-][PH2]=O

InChI

1S/Na.H3O2P.H2O/c;1-3-2;/h;3H2,(H,1,2);1H2/q+1;;/p-1

Clave InChI

PLZNPHDJGFDNRM-UHFFFAOYSA-M

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Categorías relacionadas

Aplicación

Sodium hypophosphite monohydrate can be used as a:
  • Reducing agent in the synthesis of nickel nanoparticles (NiNP) from nickel acetate tetrahydrate under microwave irradiation.[1]
  • Hydrogen donor in the enantioselective transfer hydrogenation of aliphatic and aromatic ketones to corresponding alcohols in presence of ruthenium catalyst.[2]
  • Catalyst in esterification of spent grain to improve heavy metal ions adsorption capacity using N,N-dimethylformamide (DMF) as a solvent.[3]

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Eyeshields, Gloves, type N95 (US)


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Certificados de análisis (COA)

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Microwave assisted greener synthesis of nickel nanoparticles using sodium hypophosphite.
Eluri R and Paul B
Materials Letters, 76, 36-39 (2012)
Biphasic Glycerol/2-MeTHF, Ruthenium-Catalysed Enantioselective Transfer Hydrogenation of Ketones Using Sodium Hypophosphite as Hydrogen Donor.
Guyon C, et al.
European Journal of Organic Chemistry, 2013(24), 5439-5444 (2013)
Fast esterification of spent grain for enhanced heavy metal ions adsorption.
Li Q, et al.
Bioresource Technology, 101(10), 3796-3799 (2010)
Lukas J Goossen et al.
Chemical communications (Cambridge, England), (8)(8), 836-837 (2002-07-19)
A catalyst generated in situ from palladium acetate and tricyclohexylphosphine efficiently catalyzes the reduction of carboxylic acids with sodium hypophosphite in the presence of pivalic anhydride to give aldehydes with high selectivity. The low cost and convenient handling of the
W S Price et al.
Biophysical chemistry, 33(3), 205-215 (1989-07-01)
A 31P-NMR method, which complements earlier 13C-NMR procedures for probing the intra-erythrocyte microenvironment, is described. Hypophosphite is an almost unique probe of the erythrocyte microenvironment, since it is rapidly transported into the cell via the band 3 protein, and intra-

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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