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Merck

D9132

Sigma-Aldrich

2,2-difenil-1-picrilhidrazil

Sinónimos:

2,2-Difenil-1-(2,4,6-trinitrofenil)hidrazil, DPPH, Radical 1,1-difenil-2-picrilhidrazil

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1 G
$241.000
5 G
$355.000

$241.000


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1 G
$241.000
5 G
$355.000

About This Item

Fórmula empírica (notación de Hill):
C18H12N5O6
Número de CAS:
Peso molecular:
394.32
Beilstein:
1846081
Número CE:
Número MDL:
Código UNSPSC:
12352127
ID de la sustancia en PubChem:
NACRES:
NA.22

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Formulario

powder

Nivel de calidad

color

green

mp

~135 °C (dec.) (lit.)

temp. de almacenamiento

2-8°C

cadena SMILES

[O-][N+](=O)c1cc(c([N]N(c2ccccc2)c3ccccc3)c(c1)[N+]([O-])=O)[N+]([O-])=O

InChI

1S/C18H12N5O6/c24-21(25)15-11-16(22(26)27)18(17(12-15)23(28)29)19-20(13-7-3-1-4-8-13)14-9-5-2-6-10-14/h1-12H

Clave InChI

HHEAADYXPMHMCT-UHFFFAOYSA-N

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Descripción general

El 2,2-difenil-1-picrilhidracil es un radical libre, que muestra capacidad aceptora de hidrógenos hacia los antioxidantes.[1] Por consiguiente, se utiliza habitualmente en el análisis DPPH para medir la actividad antioxidante de diferentes muestras naturales, como el vino, las frutas[2], el te de hierbas, etc[3].

Aplicación

  • Radical-p 2,2-difenil-1-picrilhidracil (DPPH) estable adsorbido en los codos de Au reconstruido 22 x 3 (111): este estudio se centra en la investigación al nivel molecular del radical orgánico estable DPPH, explorando sus características de adsorción e interacción en una superficie de oro, lo cual es crucial para entender fenómenos magnéticos sin metales a escala subnanométrica (R Vranik et al., 2020).

Otras notas

Radical libre

Producto relacionado

Referencia del producto
Descripción
Precios

Palabra de señalización

Danger

Clasificaciones de peligro

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Self-react. C - Skin Irrit. 2 - Skin Sens. 1

Código de clase de almacenamiento

4.1A - Other explosive hazardous materials

Clase de riesgo para el agua (WGK)

WGK 1

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable


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Certificados de análisis (COA)

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Visite la Librería de documentos

Influence of solvent composition on antioxidant potential of model polyphenols and red wines determined with 2, 2-diphenyl-1-picrylhydrazyl.
Bertalanic L, et al.
Journal of Agricultural and Food Chemistry, 60(50), 12282-12288 (2012)
Determination of in vitro antidiabetic effects, antioxidant activities and phenol contents of some herbal teas.
Buyukbalci A and Sedef Nehir El.
Plant Foods For Human Nutrition, 63(1), 27-33 (2008)
Studies on the antioxidants. XIII. Hydrogen donating capability of antioxidants to 2, 2-diphenyl-1-picrylhydrazyl.
KuREcHI T, et al.
Chemical & Pharmaceutical Bulletin, 28(7), 2089-2093 (1980)
Jiahao Huang et al.
Pharmaceutics, 11(4) (2019-04-17)
Phyto-phospholipid complexes have been developed as a common way of improving the oral bioavailability of poorly absorbable phyto-pharmaceuticals; however, the complexation with phospholipids can induce positive or negative effects on the bioaccessibility of such plant-derived active ingredients in different parts
Višnja Stepanić et al.
Antioxidants (Basel, Switzerland), 8(4) (2019-04-10)
Chalcones are polyphenolic secondary metabolites of plants, many of which have antioxidant activity. Herein, a set of 26 synthetic chalcone derivatives with alkyl substituted pyrazine heterocycle A and four types of the monophenolic ring B, were evaluated for the potential

Questions

1–7 of 7 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  3. How to use DPPH to detect quantity of antioxidant in cosmetic sample ? Do you have any method?

    1 answer
    1. This product is not tested for activity, however there are a number of publications available that focus on this assay. Please see the link below for an example: https://www.sciencedirect.com/science/article/pii/S1756464615000511

      Helpful?

  4. What is the solubility of 2,2-Diphenyl-1-picrylhydrazyl, DPPH, Product D9132?

    1 answer
    1. We would expect this material to be soluble in chloroform and methanol. Quality control testing shows that a concentration of about 50mg/mL in chloroform can be achieved.

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  5. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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  6. At what wavelength is the absorbance maximum (lambda max) for 2,2-Diphenyl-1-picrylhydrazyl, DPPH, Product D9132?

    1 answer
    1. Using chloroform as the solvent, the lambda max is approximately 332 nm.

      Helpful?

  7. What is the extinction coefficient of 2,2-Diphenyl-1-picrylhydrazyl, DPPH, Product D9132?

    1 answer
    1. The millimolar extinction coefficient (EmM) has been reported to be 19.07 in chloroform, measured at a wavelength of 332 nm. Reference: Organic Electronic Spectra Data (OESD), 1, p. 753 (1946-1952).

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