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109207

Sigma-Aldrich

2-Methyl-2-propanethiol

99%

Sinónimos:

tert-Butyl mercaptan, TBM

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About This Item

Fórmula lineal:
(CH3)3CSH
Número de CAS:
75-66-1
Peso molecular:
90.19
Beilstein/REAXYS Number:
505947
EC Number:
200-890-2
MDL number:
MFCD00004857
UNSPSC Code:
12352100
PubChem Substance ID:
24846894
NACRES:
NA.22

vapor density

3.1 (vs air)

Quality Level

100

vapor pressure

303.5 mmHg ( 37.7 °C)

assay

99%

refractive index

n20/D 1.423 (lit.)

bp

62-65 °C (lit.)

mp

-0.5 °C (lit.)

solubility

H2O: slightly soluble
alcohol: very soluble
diethyl ether: very soluble

density

0.8 g/mL at 25 °C (lit.)

SMILES string

CC(C)(C)S

InChI

1S/C4H10S/c1-4(2,3)5/h5H,1-3H3

InChI key

WMXCDAVJEZZYLT-UHFFFAOYSA-N

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General description

2-Methyl-2-propanethiol undergoes ring opening nucleophilic reaction with 3-isothiazolones and reaction kinetics studies suggested reaction was second order in thiol and third order overall.

Application

2-Methyl-2-propanethiol was used in reaction of 2-methyl-2-propanethiol on Mo(110) using temperature programmed reaction, high resolution electron enegy loss and X-ray photoelectron spectroscopies. It was used in the synthesis of chain-transfer agents for reversible addition-fragmentation chain-transfer copolymerization of vinylidene chloride and methyl acrylate.

signalword

Danger

Hazard Classifications

Aquatic Chronic 2 - Flam. Liq. 2 - Skin Sens. 1B

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

<-13.0 °F - closed cup

flash_point_c

< -25 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

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Christian Ledig et al.
Scientific reports, 8(1), 11258-11258 (2018-07-28)
Magnetic resonance (MR) imaging is a powerful technique for non-invasive in-vivo imaging of the human brain. We employed a recently validated method for robust cross-sectional and longitudinal segmentation of MR brain images from the Alzheimer's Disease Neuroimaging Initiative (ADNI) cohort.
Qunxi Dong et al.
NeuroImage. Clinical, 22, 101744-101744 (2019-03-11)
Apolipoprotein E (APOE) e4 is the major genetic risk factor for late-onset Alzheimer's disease (AD). The dose-dependent impact of this allele on hippocampal volumes has been documented, but its influence on general hippocampal morphology in cognitively unimpaired individuals is still
Arjan van Laarhoven et al.
The Journal of infectious diseases, 215(7), 1029-1039 (2017-04-19)
Damaging inflammation is thought to contribute to the high morbidity and mortality of tuberculous meningitis (TBM), but the link between inflammation and outcome remains unclear. We performed prospective clinical and routine laboratory analyses of a cohort of adult patients with
Laura Seynaeve et al.
NeuroImage. Clinical, 21, 101657-101657 (2019-01-21)
Transcranial magnetic stimulation (TMS) is a useful technique to help localize motor function prior to neurosurgical procedures. Adequate modelling of the effect of TMS on the brain is a prerequisite to obtain reliable data. Twelve patients were included with perirolandic
Ursula K Rohlwink et al.
Nature communications, 10(1), 3767-3767 (2019-08-23)
Tuberculous meningitis (TBM) is the most severe form of TB with high rates of mortality and morbidity. Here we conduct RNA-sequencing on whole blood as well as on ventricular and lumbar cerebrospinal fluid (CSF) of pediatric patients treated for TBM.
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