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T28002

Sigma-Aldrich

Thioanisole

ReagentPlus®, ≥99%

Sinonimo/i:

Methyl phenyl sulfide

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About This Item

Formula condensata:
C6H5SCH3
Numero CAS:
100-68-5
Peso molecolare:
124.20
Beilstein:
1904179
Numero CE:
202-878-2
Numero MDL:
MFCD00008559
Codice UNSPSC:
12352100
ID PubChem:
57654663
NACRES:
NA.21

Livello qualitativo

200

Nome Commerciale

ReagentPlus®

Saggio

≥99%

Indice di rifrazione

n20/D 1.587 (lit.)

P. eboll.

188 °C (lit.)

Punto di fusione

−15 °C (lit.)

Densità

1.057 g/mL at 20 °C (lit.)

Stringa SMILE

CSc1ccccc1

InChI

1S/C7H8S/c1-8-7-5-3-2-4-6-7/h2-6H,1H3
HNKJADCVZUBCPG-UHFFFAOYSA-N

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Categorie correlate

Applicazioni

Thioanisole may be used in the synthesis of methyl phenyl sulfoxide via oxidation.

Note legali

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Pittogrammi

Exclamation markEnvironment
GHS07,GHS09

Avvertenze

Warning

Indicazioni di pericolo

H315,H317,H319,H411

Classi di pericolo

Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1B

Codice della classe di stoccaggio

10 - Combustible liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

163.4 °F - closed cup

Punto d’infiammabilità (°C)

73 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
STBL3952
STBH5431
STBG8672
STBJ6225
STBK8402

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Mild and selective oxidation of sulfur compounds in trifluoroethanol: diphenyl disulfide and methyl phenyl sulfoxide.
Ravikumar KS, et al.
Organic Syntheses, 184-189 (2003)
Methyl phenyl sulfoxide.
Johnson CR & Keiser JE.
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The electronic and structural features of (oxo)manganese(V) corroles and their catalyzed oxygen atom transfers to thioanisole in different spin states have been investigated by the B3LYP functional calculations. Calculations show that these corrole-based oxidants and their complexes with thioanisole generally
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Organic & biomolecular chemistry, 7(16), 3208-3211 (2009-07-31)
Two new artificial hemoproteins or "hemozymes", obtained by non covalent insertion of Fe(III)-meso-tetra-p-carboxy- and -p-sulfonato-phenylporphyrin into xylanase A from Streptomyces lividans, were characterized by UV-visible spectroscopy and molecular modeling studies, and were found to catalyze the chemo- and stereoselective oxidation
Jiyun Park et al.
Journal of the American Chemical Society, 133(14), 5236-5239 (2011-03-18)
The mechanism of sulfoxidation of thioaniosoles by a non-heme iron(IV)-oxo complex is switched from direct oxygen transfer to metal ion-coupled electron transfer by the presence of Sc(3+). The switch in the sulfoxidation mechanism is dependent on the one-electron oxidation potentials
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