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Documenti fondamentali

60591

Supelco

Potassium tetrakis(4-chlorophenyl)borate

for ion-selective electrodes, Selectophore, ≥98.0%

Sinonimo/i:

Tetrakis(4-chlorophenyl)boron potassium

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About This Item

Formula condensata:
(ClC6H4)4BK
Numero CAS:
Peso molecolare:
496.11
Beilstein:
4117827
Numero CE:
Numero MDL:
Codice UNSPSC:
26111700
ID PubChem:
NACRES:
NB.61

Grado

for ion-selective electrodes

Livello qualitativo

Nome Commerciale

Selectophore

Saggio

≥98.0% (AT)
≥98.0%

Stato

solid

Stringa SMILE

[K+].Clc1ccc(cc1)[B-](c2ccc(Cl)cc2)(c3ccc(Cl)cc3)c4ccc(Cl)cc4

InChI

1S/C24H16BCl4.K/c26-21-9-1-17(2-10-21)25(18-3-11-22(27)12-4-18,19-5-13-23(28)14-6-19)20-7-15-24(29)16-8-20;/h1-16H;/q-1;+1
SAGICZRAKJSWLD-UHFFFAOYSA-N

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Descrizione generale

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Applicazioni

Potassium tetrakis(4-chlorophenyl)borate was used as lipophilic anionic site in constructing fluorescent optode for sodium. It was also used as coating for the piezoelectric crystal in quantifying Potassium using quartz crystal microbalance.

Confezionamento

Bottomless glass bottle. Contents are inside inserted fused cone.

Note legali

Selectophore is a trademark of Merck KGaA, Darmstadt, Germany

Pittogrammi

Skull and crossbones

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 3 Oral

Codice della classe di stoccaggio

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves


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Correct measurement of the pH in highly acidic environments is still a challenge. In such conditions most of the pH indicators suffer from instability in air or leaching from host matrices due to the solubility considerations. In this work, two
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Transport of the prototypical organic cation tetraethylammonium (TEA) by the Malpighian tubules, ureters and gut of Drosophila melanogaster was studied using two novel electrophysiological techniques. Both techniques exploited the high selectivity of the cation exchanger potassium tetra-p-chlorophenylborate for tetraalkylammonium compounds
X Yang et al.
Talanta, 52(6), 1033-1039 (2008-10-31)
A fluorescent optode membrane for sodium ion that works on the basis of a cation-exchange mechanism has been developed. The plasticized poly(vinyl chloride) (PVC) membrane incorporating sodium-selective ionophore (4-tert-butylcalix[4]arene tetraacetic acid tetraethyl ester), acidic fluorescent pH indicator (5,10,15,20-tetraphenylporphine, TPP) and
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The metalloporphyrin ligand bearing incorporated anion-exchanger fragment, 5-[4-(3-trimethylammonium)propyloxyphenyl]-10,15,20-triphenylporphyrinate of Co(II) chloride, CoTPP-N, has been tested as anion-selective ionophore in PVC-based solvent polymeric membrane sensors. A plausible sensor working mechanism includes the axial coordination of the target anion on ionophore metal
R C Thomas et al.
Pflugers Archiv : European journal of physiology, 390(1), 96-98 (1981-04-01)
We have developed a filling solution for silanised microelectrodes consisting of potassium tetrakis (p-chlorophenyl) borate in octanol. Microelectrodes filled with this reference liquid ion-exchanger (RLIE) have equal selectivities to Na and K, and give the same membrane potential as do

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