900399

SLAP N-Bn Pip Reagent

95%

• Sinonimo/i: N¹-Benzyl-N¹-((trimethylsilyl)methyl)ethane-1,2-diamine
• Formula empirica (notazione di Hill): C₁₃H₂₄N₂Si
• Numero CAS: 1908469-38-4
• Peso molecolare: 236.43
• Codice UNSPSC: 12352200
• ID PubChem: 329769827
• NACRES: NA.22

Proprietà

• Livello qualitativo: 100
• Saggio: 95%
• Forma fisica: liquid (paste)
• Indice di rifrazione: n/D 1.5071
• Densità: 0.9366 g/mL
• Temperatura di conservazione: −20°C

Descrizione

Applicazioni

Silicon amine protocol (SLAP) reagents, in conjunction with aldehydes and ketones, form N-unprotected piperazines via photocatalytic cross-coupling with Ir[(ppy)₂dtbbpy]PF₆ (747769). Heteroaromatic, aromatic, and aliphatic aldehydes are well tolerated, as are structurally and stereochemically complex SLAP reagents. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents for piperazine synthesis.

Altre note

• Technology Spotlight: SLAP Reagents for Piperazine Synthesis
• Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones
• Lewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents.
• Continuous Flow Synthesis of Morpholines and Oxazepanes with Silicon Amine Protocol (SLAP) Reagents and Lewis Acid Facilitated Photoredox Catalysis

Informazioni sulla sicurezza

• Pittogrammi: GHS07
• Avvertenze: Warning
• Indicazioni di pericolo: H315,H319,H335
• Consigli di prudenza: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Classi di pericolo: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Organi bersaglio: Respiratory system
• Codice della classe di stoccaggio: 10 - Combustible liquids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): 198.0 °F
• Punto d’infiammabilità (°C): 92.2 °C