![9-Azabicyclo[3.3.1]nonane N-oxyl 95%](/deepweb/assets/sigmaaldrich/product/structures/287/155/e2f4a2e1-1d4e-4bed-9187-9e16d23cbbbf/640/e2f4a2e1-1d4e-4bed-9187-9e16d23cbbbf.png)
AZADO (2-azaadamantane N-oxyl) can convert alcohols to their corresopnding carbonyl compounds more effectively than the traditional TEMPO reagent in sterically hindered environments.
701718
2-Azaadamantane-N-oxyl
90%
Sinonimo/i:
AZADO
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50 MG
CHF 192.00
250 MG
CHF 630.00
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Cambia visualizzazione
50 MG
CHF 192.00
250 MG
CHF 630.00
About This Item
Formula empirica (notazione di Hill):
C9H14NO
Numero CAS:
Peso molecolare:
152.21
Numero MDL:
Codice UNSPSC:
12352000
ID PubChem:
NACRES:
NA.22
Prodotti consigliati
Livello qualitativo
Saggio
90%
Stato
powder
Impiego in reazioni chimiche
reagent type: oxidant
Punto di fusione
182-189 °C (D)
Temperatura di conservazione
2-8°C
Stringa SMILE
[O]N1[C@@H]2C[C@H]3C[C@@H](C2)C[C@@H]1C3
InChI
1S/C9H14NO/c11-10-8-2-6-1-7(4-8)5-9(10)3-6/h6-9H,1-5H2/t6-,7+,8-,9+
BCJCJALHNXSXKE-SPJNRGJMSA-N
Categorie correlate
Descrizione generale
2-Azaadamantane-N-oxyl (AZADO), a stable nitroxyl radical, is widely employed as catalyst for the oxidation of alcohols.[1]
Avvertenze
Warning
Indicazioni di pericolo
Classi di pericolo
Acute Tox. 4 Oral
Codice della classe di stoccaggio
11 - Combustible Solids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
Not applicable
Punto d’infiammabilità (°C)
Not applicable
Dispositivi di protezione individuale
dust mask type N95 (US), Eyeshields, Gloves
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Journal of the American Chemical Society, 128(26), 8412-8413 (2006-06-29)
Development of a stable nitroxyl radical class of catalysts, 2-azaadamantane N-oxyl (AZADO) and 1-Me-AZADO, for highly efficient oxidation of alcohols is described. AZADO and 1-Me-AZADO exhibit superior catalytic proficiency to TEMPO, converting various sterically hindered alcohols to the corresponding carbonyl
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Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
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